Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 50, Pages 17649-17651Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja105631j
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Funding
- foundation of the Kinki Regional Invention Center
- Grants-in-Aid for Scientific Research [22655033, 22750107] Funding Source: KAKEN
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We report the synthesis of a stable room-temperature ionic liquid consisting of an octacarboxy polyhedral oligomeric silsesquioxane (POSS) anion and an imidazolium cation. The introduction of the POSS moiety enhances the thermal stability and reduces the melting temperature. From an evaluation of the thermodynamic parameters during the melting, it was found that the rigidity and cubic structure of FOSS can contribute to the enhancement of these thermal properties.
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