4.8 Article

A Cysteine-Based Tripodal Chelator with a High Affinity and Selectivity for Copper(I)

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 20, Pages 6928-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja901700a

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Funding

  1. Cluster de recherche Chimie de lit Region Rhone-Alpes

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A C-3-symmetric ligand containing three converging cysteine chains anchored on a nitrilotriacetic acid moiety has been synthesized. This tripodal pseudopeptide, which provides three soft sulfur donor groups, exhibits a very high affinity for Cu(I) in either a monometallic complex or the cluster species Cu6L3.

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