Article
Chemistry, Physical
Tadeusz Bak, Turgut M. Gur, Janusz Nowotny
Summary: This work explores the use of a high-temperature electron probe to understand the surface and bulk properties of materials for energy application. The focus is on surface defect engineering of TiO2-O2 model system, which plays a crucial role in the reactivity of solids and performance in energy conversion devices. The studies conducted in situ and in operando under real application conditions are expected to contribute to the rational design of surface properties for high-performance energy materials.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Duoyue Tang, Zewen Shen, Sebastian Lechler, Guilong Lu, Ling Yao, Yezi Hu, Xiubing Huang, Martin Muhler, Guixia Zhao, Baoxiang Peng
Summary: In this study, an environmentally friendly catalytic approach using oxygen vacancies-enriched titanium-based oxides and water as solvent at room temperature for the lactonization of various aromatic and aliphatic diols was reported. The results showed that oxygen vacancies as strong Lewis acid sites played a pivotal role in the superior catalytic activities at room temperature, attributed to the enhanced reaction rate of the lactonization process.
JOURNAL OF CATALYSIS
(2023)
Article
Biochemistry & Molecular Biology
Mairis Iesalnieks, Raivis Eglitis, Talis Juhna, Krisjanis Smits, Andris Sutka
Summary: This study successfully prepared a transparent titanium dioxide coating on plastic substrates and demonstrated its high performance in photocatalytic degradation of organic pollutants. The coating can be applied to polymer substrates and exhibits good stability.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Chemistry, Multidisciplinary
Dashui Yuan, Yiwei Jiao, Zongyuan Li, Xueru Chen, Jing Ding, Wei-Lin Dai, Hui Wan, Guofeng Guan
Summary: Proper interfacial electron mediators play a crucial role in enhancing the charge transfer efficiency of Z-scheme photocatalytic systems. The CNNS/TiN/TiO2-x heterojunction composites show significantly improved visible light catalytic hydrogen evolution performance, with TiN acting as an electron mediator and TiO2-x providing extra visible light absorption capacity.
ADVANCED MATERIALS INTERFACES
(2021)
Article
Chemistry, Physical
Canhui Wang, Wei-Chang D. Yang, David Raciti, Alina Bruma, Ronald Marx, Amit Agrawal, Renu Sharma
Summary: This study demonstrates that endothermic reactions requiring higher activation energy can be initiated at room temperature using deep-UV localized surface plasmons. By exciting multiple localized surface plasmon modes, the reduction of CO2 to CO by carbon was successfully achieved at room temperature.
Article
Nanoscience & Nanotechnology
Mostafa Shooshtari, Sten Vollebregt, Yas Vaseghi, Mahshid Rajati, Saeideh Pahlavan
Summary: Detection of hazardous toxic gases for air pollution monitoring and medical diagnosis has been researched. In this paper, a Titanium dioxide (TiO2)-based gas sensor enhanced with gold nanoparticles was fabricated and characterized. The presence of gold nanoparticles on the surface of TiO2 was found to enhance the sensitivity response of gas sensors by up to about 40%. The fabricated gas sensor showed sensitivity to acetone, methanol, and ethanol vapors at room temperature and the recovery time of the gold decorated TiO2 sensor was less than 40 seconds.
Article
Chemistry, Physical
M. Stefan, C. Leostean, D. Toloman, A. Popa, S. Macavei, A. Falamas, R. Suciu, L. Barbu-Tudoran, O. Marincas, O. Pana
Summary: In this study, CoFe2O4/TiO2:Tb composite nanoparticles were synthesized by a chemical method, and it was found that there was a spin transfer between TiO2 and cobalt ferrite, resulting in ordered magnetic moments of oxygen vacancies in TiO2. The magnetic moments of Tb ions could have different coupling states depending on the dopant concentration, and the magnetically ordered interface transferred states helped increase the lifetime of photoexcited electrons.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
Wei-Hsiang Huang, Chin-Jung Lin, Tsung-Han Huang, Chia-Yu Chang, Shu-Chih Haw, Hwo-Shuenn Sheu, Shih-Yun Chen, Chung-Li Dong, Krishna Kumar, Bing Joe Hwang, Wei-Nien Su, Chi-Liang Chen
Summary: In this study, Fe(III) ions were incorporated into TiO2 hollow submicrospheres, which served as an excellent photocatalyst. The experimental parameters such as flow rate, rotation speed, and contaminant concentration were found to improve the catalyst activity. Fe-TiO2 hollow submicrospheres with different Fe wt% were prepared, and it was discovered that 2.5 wt% Fe-TiO2 exhibited the best photocatalyst activity. The Fe(III) doping not only increased the interaction between transition metal (Fe and Ti) 3d orbitals in TiO2, but also promoted the Fe(III)/Fe(II) redox kinetics and the associated photo-Fenton degradation of acetaminophen.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Hao Wang, Yao Wen, Xiaoxu Zhao, Ruiqing Cheng, Lei Yin, Baoxing Zhai, Jian Jiang, Zhongwei Li, Chuansheng Liu, Fengcheng Wu, Jun He
Summary: The heteroepitaxial growth of ferromagnetic CuCr2Te4 nanosheets on Cr2Te3 and mica by chemical vapor deposition is reported. The CuCr2Te4 nanosheets on mica exhibit thickness-dependent ferromagnetism with a decrease in Curie temperature (T-C) and an enhancement of perpendicular magnetic anisotropy. Moreover, the lattice-matched heteroepitaxial ultrathin CuCr2Te4 on Cr2Te3 shows an enhanced robust ferromagnetism with an increased T-C due to interfacial charge transfer. This work provides a method to construct robust room-temperature 2D magnetic heterostructures for functional spintronic devices.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Analytical
Levani Skhirtladze, Karolis Leitonas, Audrius Bucinskas, Kai Lin Woon, Dmytro Volyniuk, Rasa Keruckiene, Malek Mahmoudi, Mieczyslaw Lapkowski, Azhar Ariffin, Juozas Grazulevicius
Summary: A series of compounds with different donor moieties and 1,4-difluorobenzene unit as the acceptor were developed for optical sensors of oxygen. One compound, 2PS-2FPh, exhibited high sensitivity to low concentration of oxygen and showed strong room-temperature phosphorescence in a rigid matrix Zeonex. The increased molecular heterogeneity and the transformation of the hybrid local and charge transfer triplet state into locally excited triplet states were found to be the reasons for the high oxygen sensitivity of 2PS-2FPh.
SENSORS AND ACTUATORS B-CHEMICAL
(2023)
Article
Chemistry, Multidisciplinary
Keisuke Fujita, Masataka Ijiri, Yoichi Inoue, Shoichi Kikuchi
Summary: Heating in a nitrogen atmosphere can improve the tribological properties of titanium alloys but reduces their strength. A rapid nitriding method involves bombarding the surface of a titanium alloy with commercially pure titanium fine particles with a nitrided phase at room temperature, forming a nitrided layer within a short period. This method resolves the trade-off between the rapid formation of a nitrided layer and the suppression of grain coarsening for titanium alloys.
ADVANCED MATERIALS
(2021)
Article
Engineering, Environmental
Saehan Choi, Jeonga Kim, Rafia Tasnim Rahman, Dong Jae Lee, Kimoon Lee, Yoon Sung Nam
Summary: This study presents plastic-free silica-titania-tannin hybrids that enhance the blocking effects of UV-to-blue light while suppressing the generation of reactive oxygen species (ROS). The results demonstrate the promising application of these hybrids in protecting the skin from UV and blue light-induced damage.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Energy & Fuels
Guojun Dong, Xiang Cheng, Yingpu Bi
Summary: A hierarchical bottom-up approach for fabricating TiO2 nanorod arrays with an Au nanolayer and Sn3O4 cocatalysts is demonstrated in this study, showing significantly enhanced photocurrent density under AM 1.5G irradiation. The enhanced PEC properties are attributed to spatial charge separation among the Au nanolayer and Sn3O4 cocatalysts, offering new insights for rational design and construction of highly efficient TiO2-based PEC devices for solar water splitting.
Article
Biochemistry & Molecular Biology
Andrii Tarasov, Federico Garzelli, Christoph Schuessler, Stefanie Fritsch, Christophe Loisel, Alexandre Pons, Claus-Dieter Patz, Doris Rauhut, Rainer Jung
Summary: Storage temperature plays a key role in wine aging, impacting the evolution of primary and secondary aromas, wine color, and low molecular weight sulfur compounds. The levels of SO2 and CO2 in the bottle's headspace mainly affect specific compounds, while different stopper types do not significantly affect wine preservation properties.
Article
Biochemistry & Molecular Biology
Shuxian Weng, Guixin Zhang, Yun Hu, Caiying Bo, Fei Song, Guodong Feng, Lihong Hu, Yonghong Zhou, Puyou Jia
Summary: This study presents a green and mild approach for the degradation of lignin using chlorine dioxide under acidic aqueous conditions at room temperature. The results showed that lignin could be effectively degraded to form quinones and muconic acids. Additionally, the presence of NaBH4 reduced the degrated intermediate lignin (DIL) to substances with a high phenolic-hydroxyl content.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Chemistry, Physical
Kazi A. Rahman, A. Atanacio, M. Ionescu, J. Davis, T. Bak, J. Nowotny
Review
Materials Science, Multidisciplinary
Kunkun Fu, Leigh R. Sheppard, Li Chang, Xianghai An, Chunhui Yang, Lin Ye
MATERIALS CHARACTERIZATION
(2018)
Review
Green & Sustainable Science & Technology
Janusz Nowotny, John Dodson, Sebastian Fiechter, Turgut M. Gur, Brendan Kennedy, Wojciech Macyk, Tadeusz Bak, Wolfgang Sigmund, Michio Yamawaki, Kazi A. Rahman
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2018)
Article
Engineering, Mechanical
Kunkun Fu, Leigh Sheppard, Li Chang, Xianghai An, Chunhui Yang, Lin Ye
TRIBOLOGY INTERNATIONAL
(2018)
Article
Materials Science, Coatings & Films
I. I. Kabir, L. R. Sheppard, R. Liu, Y. Yao, Q. Zhu, W. -F. Chen, P. Koshy, C. C. Sorrell
SURFACE & COATINGS TECHNOLOGY
(2018)
Article
Chemistry, Multidisciplinary
Hangjuan Ren, Thomas Dittrich, Hongyang Ma, Judy N. Hart, Steffen Fengler, Sheng Chen, Yibing Li, Yu Wang, Fuyang Cao, Mauricio Schieda, Yun Hau Ng, Zhirun Xie, Xin Bo, Pramod Koshy, Leigh R. Sheppard, Chuan Zhao, Charles C. Sorrell
ADVANCED MATERIALS
(2019)
Article
Chemistry, Physical
Kazi A. Rahman, N. Sharma, A. J. Atanacio, T. Bak, E. D. Wachsman, M. Moffitt, J. Nowotny
Article
Materials Science, Multidisciplinary
L. R. Sheppard, H. Zhang, R. Liu, S. Macartney, T. Murphy, R. Wuhrer
MATERIALS CHEMISTRY AND PHYSICS
(2019)
Article
Materials Science, Multidisciplinary
L. R. Sheppard, H. Zhang, R. Liu, S. Macartney, T. Murphy, P. Wainer, R. Wuhrer
MATERIALS CHEMISTRY AND PHYSICS
(2019)
Review
Chemistry, Physical
Leigh R. Sheppard, Richard Wuhrer
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2020)
Article
Materials Science, Multidisciplinary
I. I. Kabir, L. R. Sheppard, R. Shamiri, P. Koshy, R. Liu, W. Joe, A. Le, X. Lu, W. -F. Chen, C. C. Sorrell
JOURNAL OF MATERIALS SCIENCE
(2020)
Article
Materials Science, Coatings & Films
Haoruo Zhou, Li Chang, Kunkun Fu, Hao Huang, Ranming Niu, Xiaozhou Liao, Leigh Sheppard, Laurel George, Ludvik Martinu
SURFACE & COATINGS TECHNOLOGY
(2020)
Article
Chemistry, Physical
Amanda Chen, Wen-Fan Chen, Tina Majidi, Bernadette Pudadera, Armand Atanacio, Madhura Manohar, Leigh R. Sheppard, Rong Liu, Charles Christopher Sorrell, Pramod Koshy
Summary: Uniformly codoped anatase TiO2 thin films with equal Mo and Cr concentrations were fabricated using sol-gel spin coating and ion implantation. Both methods did not result in homogeneous dopant distributions, leading to decreased crystallinities and partial amorphisation. The photocatalytic performances of the films were poor and correlated with the band gap, indicating the effects of different doping methods on performance.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Correction
Materials Science, Multidisciplinary
I. I. Kabir, L. R. Sheppard, R. Shahmiri, P. Koshy, R. Liu, W. Joe, A. Le, X. Lu, W. -F. Chen, C. C. Sorrell
JOURNAL OF MATERIALS SCIENCE
(2021)
Article
Chemistry, Physical
Tadeusz Bak, Eric D. Wachsman, Kathryn E. Prince, Kazi A. Rahman, Janusz Nowotny
ACS APPLIED ENERGY MATERIALS
(2019)