Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 18, Pages 5834-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja710267u
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This Communication reports simultaneous tracking of structural and kinetic information for the photoinduced elimination reaction of 1,2-diiodotetrafluoroethane in solution by transient X-ray diffraction. The transient structure of center dot CF2CF2I is determined to be a classical mixture whereas center dot CH2CH2I is bridged. Compared with the gas phase reaction, the secondary dissociation of center dot CF2CF2I into C2F4 and I is slowed down by a factor of 6 in solution. Transient X-ray diffraction offers a complementary method for capturing transient structures in solution which might be invisible or optically silent in time-resolved optical spectroscopy.
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