4.8 Article

Lewis acid promoted carbon-carbon bond cleavage of γ-silyloxy-β-hydroxy-α-diazoesters

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 12, Pages 3766-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja801004d

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Cyclic gamma-silyloxy-beta-hydroxy-alpha-diazoesters undergo efficient rupture of the C beta-C gamma bond when treated with fin tetrachloride to provide tethered aldehyde ynoate products in high geld.

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