Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 130, Issue 7, Pages 2158-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja710273s
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The bifunctional chiral amido Ir complex catalyzed asymmetric electrophilic direct amination of alpha-substituted alpha-cyanoacetates using azodicarboxylates proceeds rapidly to provide the corresponding hydrazine adducts in high yields and with excellent ea values.
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