4.7 Article

Low-Temperature Synthesis of Nanocrystalline NbB2 Powders by Borothermal Reduction in Molten Salt

Journal

JOURNAL OF THE AMERICAN CERAMIC SOCIETY
Volume 97, Issue 11, Pages 3384-3387

Publisher

WILEY-BLACKWELL
DOI: 10.1111/jace.13298

Keywords

-

Funding

  1. Innovation Fund Project for Graduate Student
  2. Student Research Training Program (SRTP) of Anhui University of Technology
  3. Natural Science Foundation of Anhui Provincial Education Department [KJ2012A044]
  4. National Natural Science Foundation of China [51302002, 91226202]
  5. Natural Science Foundation of Anhui Province [1308085QE73]

Ask authors/readers for more resources

Nanocrystalline NbB2 powders were successfully prepared by borothermal reduction in molten salt at 800 degrees C-1000 degrees C. Due to the more homogeneous mixing and more rapid diffusion of species in the liquid state than in the solid state, the synthesis temperature of pure NbB2 phase was greatly decreased by the presence of molten NaCl/KCl salt. The NbB2 powders synthesized at 1000 degrees C had the largest specific surface area of 27.09m(2)/g and the lowest equivalent average particle size of 32nm, respectively.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

Confining Aqueous Zn-Br Halide Redox Chemistry by Ti3C2Tx MXene

Xinliang Li, Na Li, Zhaodong Huang, Ze Chen, Yuwei Zhao, Guojin Liang, Qi Yang, Mian Li, Qing Huang, Binbin Dong, Jun Fan, Chunyi Zhi

Summary: This study introduces an advanced aqueous zinc redox battery by incorporating an electrochemically active parasite Br-2 into the Ti3C2Tx MXene host. The battery delivers efficient output capability in the high-voltage region and shows excellent cycling performance at low temperatures.

ACS NANO (2021)

Article Materials Science, Ceramics

Joining of Ti-coated monolithic SiC using a SiCw/Ti3SiC2 filler by electric field-assisted sintering

Teng Yu, Heejin Kwon, Linkun Shi, Xiaobing Zhou, Dang-Hyok Yoon, Peter Tatarko, Xin Xu, Zhengren Huang, Qing Huang

Summary: Monolithic SiC was successfully joined using a SiC whisker-reinforced Ti3SiC2 composite filler via electric field-assisted sintering technique, achieving a joint strength higher than 250 MPa. Optimization of process parameters and the addition of up to 15 wt. % SiC whiskers improved joint strength, but a lower joint strength was observed with 20 wt. % SiC whisker addition due to thermal expansion mismatch.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2021)

Article Materials Science, Ceramics

Effect of A-site atom on static corrosion behavior and irradiation damage of Ti2SC phases

Ke Chen, Xudong Wang, Jianning Zhang, Haoming Ding, Youbing Li, Yujie Song, Fangfang Ge, Xiaobing Zhou, Shiyu Du, Qing Huang

Summary: MAX phases are a family of damage-tolerant structural materials used in the nuclear energy industry. Ti2SC phase has shown good corrosion resistance to concentrated hydrofluoric acid, potentially making it suitable for use in molten salt reactors.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2022)

Article Polymer Science

Poly(cyclosiloxane-carborane)s for harsh environments

Lihua Zhao, Tianhao Li, Bijie Wang, Ke Chen, Xiao Hu, Ming Liu, Liu He, Qing Huang, Yujie Song

Summary: Poly(siloxane-carborane)s are polymeric materials with good thermal stability and anti-oxidation properties, which can be used to protect carbon fiber and carbon foam from damage in harsh environments.

POLYMER CHEMISTRY (2022)

Article Nanoscience & Nanotechnology

Degradable Ti3C2Tx MXene Nanosheets Containing a Lignin Polyurethane Photothermal Foam (LPUF) for Rapid Crude Oil Cleanup

Xiaozhen Ma, Ke Chen, Shuqi Li, Pitchaimari Gnanasekar, Yinyan Zhong, Yupeng An, Qing Luo, Qing Huang, Jin Zhu, Jing Chen, Ning Yan

Summary: In this study, MXene nanosheets were used to modify a lignin-based polyurethane foam, creating an adsorbent with high photothermal conversion performance for heavy oil recovery. The adsorbent showed high solar absorption rate and thermal conductivity, allowing it to adsorb a large amount of heavy crude oil in a short time. Moreover, the adsorbent containing MXene nanosheets can easily degrade in alkaline solutions, leaving harmless titanium dioxide nanoparticles as residues. These bio-based adsorbents exhibit excellent performance in rapid heavy oil removal, degradability, and environmental friendliness, offering a promising solution for cleaning up high-viscous crude oil spills.

ACS APPLIED NANO MATERIALS (2022)

Article Materials Science, Ceramics

Low-temperature Pr3Si2C2-assisted liquid-phase sintering of SiC with improved thermal conductivity

Jie Xu, Xiaobing Zhou, Shunrui Zou, Lu Chen, Peter Tatarko, Jian-Qing Dai, Zhengren Huang, Qing Huang

Summary: In this study, a novel Pr3Si2C2 additive was prepared and successfully applied in the liquid-phase sintering of SiC ceramics. It was found that an appropriate amount of additive could improve the sintering rate and thermal conductivity of SiC, while excessive additive could decrease the thermal conductivity due to increased interfacial thermal resistance. SiC materials with optimized amount of additive and grain boundary structure exhibited the highest thermal conductivity.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2022)

Article Chemistry, Physical

Universal Principle for Large-Scale Production of a High-Quality Two-Dimensional Monolayer via Positive Charge-Driven Exfoliation

Junhui Sun, Ziwen Cheng, Qing Huang, Heming He, Joseph S. Francisco, Shiyu Du

Summary: Based on the intrinsic characteristics of layered materials, this study introduces a universal principle for the production of intact monolayers through layer-by-layer exfoliation via positive charge doping. The universality of this exfoliation method stems from the common electronic structures of layered materials. This strategy opens the possibility of producing diverse high-quality two-dimensional monolayers on a large scale with minimal defects.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2022)

Article Materials Science, Ceramics

Preparation of liquid polycarbosilane containing vinyl ether group and its rapid curing through thiol-ene click reaction

Yuanjie Wang, Jian Gong, Xueliang Pei, Liu He, Zhengren Huang, Qing Huang

Summary: In this study, an SiC ceramic precursor, VE-LHBPCS, was designed and synthesized. The ceramic precursor was cross-linked via thiol-ene click reaction. The results showed that the VE-LHBPCS mixture could be cured within a short period of time, forming a high yield ceramic at high temperatures.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2022)

Article Materials Science, Ceramics

High-purity stoichiometric Si3N4 ceramics through trimethylsilyl-substituted polysilazanes

Tianhao Li, Wei Zhang, Liantai Duan, Ke Chen, Qing Huang, Yinsheng Li, Zhengren Huang, Liu He, Yujie Song

Summary: Trimethylsilyl-substituted polysilazanes were synthesized and utilized to fabricate high-purity stoichiometric Si3N4 ceramics through pyrolysis process. The presence of trimethylsilyl groups enhanced the stability of polysilazanes and facilitated their escape during pyrolysis, leading to reduced oxygen and carbon content in the final polymer-derived Si3N4. The resulting Si3N4 ceramics exhibited amorphous structure up to 1400 degrees C and transformed into alpha-Si3N4 at 1500 degrees C. The synergistic effect of low oxygen and carbon content contributed to the high stability of the amorphous Si3N4 ceramics at high temperatures.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2023)

Article Chemistry, Multidisciplinary

Two-Dimensional Half-Metallic and Semiconducting Lanthanide-Based MXenes

Xiaojing Bai, Yuanbin Xue, Kan Luo, Ke Chen, Qing Huang, Xian-Hu Zha, Shiyu Du

Summary: As a large family of two-dimensional materials, MXenes have attracted intensive attention in recent years. In this study, the researchers expanded the M elements of MXenes to the lanthanide series and investigated the electronic properties of lanthanide-based MXenes. The results suggest that lanthanide-based MXenes could have potential applications in spintronics and information storage, among others.

ACS OMEGA (2022)

Article Chemistry, Physical

Excellent CoOxHy/C Oxygen Evolution Catalysts Evolved from the Rapid In Situ Electrochemical Reconstruction of Cobalt Transition Metals Doped into the V2SnC MAX Phase at A Layers

Shuairu Zhu, Youbing Li, Deyu Liu, Qing Huang, Yongbo Kuang

Summary: This study proposes a potentially generalizable strategy for constructing more compact, stable, and highly active transition metal-based composite materials by alloying transition metals with carbon elements to form high-activity sites.

ACS APPLIED ENERGY MATERIALS (2022)

Article Chemistry, Inorganic & Nuclear

Polyborosilazane with Broadly Tunable Boron Content for SiBCN Ceramics

Liantai Duan, Tianhao Li, Yangzhong Zhao, Yanpei Dang, Jianning Zhang, Ke Chen, Jian Xu, Qing Huang, Chuanzhuang Zhao, Yujie Song

Summary: The high-temperature durability of SiBCN ceramics is significantly influenced by boron concentration and synthesis methods. Carborane-substituted polyborosilazanes were synthesized with a broad range of boron content up to 40 wt %, which improved the thermal stability and functional properties of the ceramics. The introduction of boron inhibited Si3N4 crystallization and increased the crystallization temperature of SiC, while B4C appeared as a new crystalline phase.

INORGANIC CHEMISTRY (2023)

Article Polymer Science

Anchoring Effect of Hyperbranched Carborane in Highly Cross-Linked Cyclosiloxane Networks toward High-Performance Polymers

Chongwen Yu, Tianhao Li, Xiao Hu, Ming Liu, Qing Huang, Liu He, Yujie Song

Summary: High-performance polymers (HPPs) have good thermal and mechanical properties and are widely used in various fields. However, traditional highly cross-linked HPPs tend to fail at high temperatures due to structural defects. This study introduced a new design strategy using a cyclosiloxane hybrid polymer (CHP) to compensate for the structural defects and improve the performance of HPPs at high temperatures.

MACROMOLECULES (2023)

Article Chemistry, Physical

Two-Dimensional MXenes Derived from Medium/High-Entropy MAX Phases M2GaC (M = Ti/V/Nb/Ta/Mo) and their Electrochemical Performance

Lu Chen, Youbing Li, Kun Liang, Ke Chen, Mian Li, Shiyu Du, Zhifang Chai, Michael Naguib, Qing Huang

Summary: This study reports the design and synthesis of Ga-containing medium/high entropy MAX phases and their corresponding MXenes. Ga atomic layer etching is carried out using a Lewis acid molten salt (CuCl2). The as-prepared (Ti1/4V1/4Nb1/4Ta1/4)(2)CTx exhibits a Li+ specific capacity of approximately 400 mAh g(-1). For (Ti1/5V1/5Nb1/5Ta1/5Mo1/5)(2)CTx, a specific capacity of 302 mAh g(-1) is achieved after 300 cycles, and high cycling stability is observed at high current densities. This work is of great significance for expanding the family members of MXenes with tunable chemistries and structures.

SMALL METHODS (2023)

Article Chemistry, Physical

Synthesis and Characterization of Medium-/High-Entropy M2SnC (M=Ti/V/Nb/Zr/Hf) MAX Phases

Lu Chen, Youbing Li, Ke Chen, Xiaojing Bai, Mian Li, Shiyu Du, Zhifang Chai, Qing Huang

Summary: Entropy stabilization is an effective method to design and explore MAX phases with outstanding properties. In this study, medium-/high-entropy MAX phases with different A elements were synthesized and their crystal structures were verified. The electrical conductivity and charge carrier mobility of these MAX phases are lower than previously reported MAX phases. The electron contribution to thermal conductivity decreases with temperature, while the phonon contribution increases. These findings suggest a composition design route for discovering new MAX phases and tuning their properties.

SMALL STRUCTURES (2022)

Article Materials Science, Ceramics

Microwave dielectric characterization and densification mechanism analysis of CaO-B2O3-SiO2 glass-ceramic/Al2O3 composites for LTCC applications

Zilong Xiong, Wenzhuo Xue, Mujun Li, Feihu Tan, Yupeng Chen, Hongyu Yu

Summary: In this study, CBS glass/Al2O3 composites were developed for LTCC applications based on a CaO-B2O3-SiO2 (CBS) glass system with a high boron content. The study revealed that the softening of glass and interfacial reaction between the glass and Al2O3 were the two most important factors affecting LTCC's densification process. Real-time shrinkage rate of LTCC during sintering was successfully simulated, and it was proven that the formation of the CaAl2(BO3)O phase played a significant role in reducing glass viscosity and promoting dense structure formation. The resulting LTCC composite exhibited excellent performance for high-frequency applications.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Response of nonstoichiometric pyrochlore composition Nd1.8Zr2.2O7.1 to electronic excitations

Saurabh Kumar Sharma, Vinita Grover, Rakesh Shukla, Abid Hussain, Ambuj Mishra, Pawan Kumar Kulriya

Summary: In this study, the disordering caused by swift heavy ion irradiation in two different compositions of pyrochlore structures was investigated. X-ray diffraction, Raman spectroscopy, and high-resolution transmission electron microscopy were used to analyze the samples before and after irradiation. It was found that both compositions underwent amorphization due to irradiation, with a slower rate observed in Nd1.8Zr2.2O7.1. The irradiation-induced modified track region in Nd1.8Zr2.2O7.1 consisted of defect-rich pyrochlore structure, anion-deficient fluorite structure, and amorphous domains.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Influence of ion-induced lattice stress and phase transition on the irradiation resistance of high-entropy ceramics

Jiabei He, Mengshan Song, Ming Yang, Miaomiao Zhu

Summary: This study investigates the influence of ion irradiation on high-entropy ceramics and finds that irradiation-induced lattice rearrangement can improve the radiation resistance of these ceramics.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Multifunctional tantalum disilicide ceramics sintered at high temperature and high pressure

Yajie Yu, Shi He, Zhengang Zhang, Haihua Chen, Peipeng Jin, Binnian Zhong, Linhui Zhang, Liping Wang, Cheng Lu

Summary: Silicide ceramics, including tantalum disilicide (TaSi2), are known for their exceptional physical properties but are limited in practical applications due to their inherent brittleness at room temperature. In this study, we successfully improved the mechanical properties of TaSi2 ceramics and increased their electrical conductivity by modifying the preparation methods and sintering conditions. These findings provide valuable insights for future applications of TaSi2 and the design of advanced ceramic materials.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Exploring the Ln-O bonding nature and charge characteristics in monazite in relation to microwave dielectric properties

Jian Li, Jia Liu, Yongcui Zhang, Wei Sun, Yang Wang, Haitao Wu, Ling Li, Chuanbing Cheng, Yingying Wang, Ke Tan, Futian Liu

Summary: Microstructure design plays a crucial role in regulating the microwave dielectric properties of materials, however, the understanding of frequency temperature stability and related micromechanism remains limited. In this study, a combination of first-principles calculations and experimental observation was used to investigate the correlation among sintering behavior, crystal structure, bonding nature, and microwave dielectric properties of LnPO(4) (Ln = Eu, Pr) ceramics. The research findings systematically clarify the optimized effect and micromechanism of lanthanides on the dielectric properties of monazite ceramics, providing insights into the design and enhancement of microwave dielectric materials.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Effect of fiber orientation on tribological properties of fiber-reinforced C/C-SiC composites mated with ceramic ball

Wenqian Pan, Xizhen Xia, Wei Zhou, Yang Li

Summary: The study investigates the frictional and wear behaviors of carbon fiber-reinforced SiC ceramic matrix composites with different fiber orientations mating with ceramic balls. The results show that fiber orientation significantly affects the friction and wear properties of the composites. Pads with randomly arranged fibers demonstrate better friction stability and lower wear volume, potentially suitable for bearing material applications. The research also explores the factors influencing the formation of continuous tribo-film and identifies abrasive wear and oxidation wear as the dominant wear mechanisms for the friction pairs.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Synthesis and sintering of MAX phases in the Zr-Al-C system

Sergey Nikolaevich Perevislov, Ilya Evgenievich Arlashkin, Valentina Leonidovna Stolyarova

Summary: This paper describes the synthesis and sintering of MAX phases in the Zr-Al-C system. Different mixtures of initial Zr/Al/C and Zr/Al/ZrC powders were used to synthesize Zr2AlC and Zr3AlC2 MAX phases. The highest content of Zr3AlC2 MAX phase was obtained using a component ratio of 1:1.5:2-51.1 vol.% of Zr/Al/ZrC powders.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

B-site internal-strain regulation engineering of tungsten bronze structural dielectric ceramics

Weijia Luo, Xubin Wang, Baiheng Bai, Jianli Qiao, Xingcong Chen, Yongzheng Wen, Jingbo Sun, Lingxia Li, Ji Zhou

Summary: This study successfully establishes the relationship between internal strain and dielectric loss by synthesizing and designing specific structure of tungsten bronze ceramics, and concludes that controlling internal strain can effectively reduce dielectric loss. This research is of great significance for the development of future all-ceramic non-Hermitian devices.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Ultrafast high-temperature sintering of ZrB2

Santanu Mondal, Juan Diego Shiraishi Lombard, Sreenivasulu Gollapudi, Carolina Tallon, Jie-Fang Li, Dwight Viehland

Summary: Ultrafast high-temperature sintering (UHS) is an effective method for rapidly densifying ZrB2 powders. The final grain size increases with longer sintering duration. X-ray diffraction and energy-dispersive spectroscopy show crystalline phase and compositional uniformity in ZrB2 after UHS.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Effects of doping on electronic structure and ion diffusion of Li2FeSiO4

JiaNan Wang, ZhiQiang Li, YongZheng Zhu, Yao Liang, Yan Cui, HuaLong Tao, Bo Song, Alexander Nikiforov, ZhiHua Zhang

Summary: First-principles calculations were performed to investigate the crystal structure, electronic structure, and ion diffusion of sulfur-doped Li2FeSiO4. The results showed that sulfur doping can improve the electronic conductivity and reduce the energy barrier for ion diffusion.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Early structural build-up behavior, setting mechanism, and nanostructure of alkali-activated GGBFS mixtures

Xiaodi Dai, Serdar Aydin, Mert Yuecel Yardimci, Gunter Reekmans, Peter Adriaensens, Geert De Schutter

Summary: This study investigates the rheological behavior, solidification process, and nanostructure changes of sodium hydroxide-activated slag (NH-AAS) and sodium silicate-activated slag (SS-AAS) pastes over time. The results show that NH-AAS and SS-AAS release similar heat and reach a similar reaction degree at their initial setting times, but have different gel structures.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Effect of resting time on rheological properties of glass bead suspensions: Depletion and bridging force among particles

Yanliang Ji, Simon Becker, Zichen Lu, Alexander Mezhov, Regine von Klitzing, Schmidt Wolfram, Dietmar Stephan

Summary: This study reveals the significant influence of resting time on the rheological properties of cement suspensions, which is closely related to non-absorbed polycarboxylate superplasticizers (PCEs) size variation. Adsorbed PCE during resting tends to bridge particles instead of dispersing them, leading to an increased yield stress.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Multiscale understanding the effect of K/Na ratio on electrical properties of high-performance KNN-based ceramics

Yifeng Huang, Xin Wang, Yinchang Ma, Xiang Lv, Jiagang Wu

Summary: This study investigates the effect of K/Na ratio on the phase structure, ferroelectric domains, and piezoelectric properties of potassium sodium niobate (KNN)-based ceramics. It reveals that high Na+ content leads to large ferroelectric domains, while high K+ content results in local polarity heterogeneity and distinct dielectric relaxational behavior. The balanced local polarity and stress heterogeneities contribute to improved piezoelectricity.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

Hierarchical porous MgAl2O4 ceramic in situ structured by hollow particles: Low-shrinkage and high-strength

Zun Xia, Yedong Rong, Hao Li, Ye Dong, Hongbo Yu, Jie Xu, Xiuhui Wang, Jinlong Yang

Summary: This study presents the synthesis of hollow MgAl2O4 particles in situ within porous ceramics, resulting in volume expansion and the formation of a hierarchical pore structure, leading to a significant improvement in compressive strength.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)

Article Materials Science, Ceramics

An exploration of lattice transformation mechanism of muscovite single crystal under EB irradiation at 0-1000 kGy

Honglong Wang, Zhiguo Sun, Faming Xia, Chenguang Yang, Xiaoguang Wang, Jintang Li, Linxu Jiang

Summary: In this study, the micro-geometry morphology variation and microstructural transformation mechanism of muscovite crystals under electron beam irradiation were explored. The results revealed the instability of the muscovite lattice under irradiation, as well as the expansion and shrinkage of the lattice with increasing dose. The study also identified changes in chemical structure and other mechanisms involved. These findings are significant for the design of radiation-resistant silicate materials and the manufacturing of electronic components used in the aerospace industry.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2024)