4.7 Article

In Situ Raman Indentation of β-Eucryptite: Characterization of the Pressure-Induced Phase Transformation

Journal

JOURNAL OF THE AMERICAN CERAMIC SOCIETY
Volume 92, Issue 4, Pages 857-863

Publisher

WILEY
DOI: 10.1111/j.1551-2916.2009.02994.x

Keywords

-

Funding

  1. National Science Foundation Ceramics Program [DMR-0746086]
  2. U.S. Department of Energy's Office of Basic Energy Sciences [DE-FG02-07ER46397]
  3. Assistant Secretary for Energy Efficiency and Renewable Energy, Vehicle Technologies Program
  4. High Temperature Materials Laboratory User Program
  5. Oak Ridge National Laboratory
  6. UT-Battelle LLC
  7. U.S. Department of Energy [DE-AC05-00OR22725]

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A pressure-induced phase transformation in the lithium aluminum silicate beta-eucryptite was studied with in situ Raman spectroscopy. Dense beta-eucryptite composites were made via powder synthesis followed by sintering. The specimens were then subjected to diamond indentation up to applied contact stresses of about 8 GPa, while collecting Raman spectra. The appearance of a Raman peak (similar to 520 cm(-1)) at a contact stress of about 3 GPa likely corresponds to the reversible phase transformation of beta-eucryptite to the orthorhombic phase epsilon-eucryptite. Loading and unloading in situ Raman indentation experiments are discussed with regards to this transformation.

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