Article
Chemistry, Physical
Fei Sun, Deyang Chen, Xingsen Gao, Jun-Ming Liu
Summary: BiFeO3, a single-phase multiferroic material, has various polymorphs and strong sensitivity to strain. Recent interest has been focused on emergent strain engineering in BiFeO3 thin films, using non-traditional methods to create new ground states and functionalities.
JOURNAL OF MATERIOMICS
(2021)
Review
Chemistry, Multidisciplinary
Bingbing Yang, Linghua Jin, Renhuai Wei, Xianwu Tang, Ling Hu, Peng Tong, Jie Yang, Wenhai Song, Jianming Dai, Xuebin Zhu, Yuping Sun, Shujun Zhang, Xiaolin Wang, Zhenxiang Cheng
Summary: This paper summarizes the development of bismuth ferrite thin films in recent years, introduces the method and challenges of chemical solution route preparation. It also proposes an all-solution chemical-solution deposition (AS-CSD) method to prepare ferroelectric films with different orientations, and studies their growth, structure, and ferroelectric properties.
Article
Chemistry, Multidisciplinary
T. K. Lin, H. W. Chang, W. C. Chou, B. A. Chen, C. R. Wang, D. H. Wei, C. S. Tu, P. Y. Chen
Summary: In this study, the crystalline structure, ferroelectricity, leakage current density, magnetic, and nanomechanical properties of BiFeO3 (BFO) films with Ce substitution were investigated. The results showed that Ce substitution improved the ferroelectric and magnetic properties of BCFO films, with an increase in remanent polarization and enhanced saturation magnetization. The BCFO films also exhibited strong anti-fatigue properties and enhanced nanomechanical characteristics influenced by grain size and phase composition.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2023)
Article
Materials Science, Coatings & Films
T. K. Lin, H. W. Chang, C. R. Wang, D. H. Wei, C. S. Tu, P. Y. Chen
Summary: This study investigated the phase constitutions, ferroelectric, magnetic, and nanomechanical characteristics of BiFeO3 films with Dy substitution. The results showed that the BDFO films exhibited desired ferroelectric and ferromagnetic properties, and the hardness of the films was controlled mainly by the impeded propagation of dislocation by grain boundary. The findings suggest that the radius and magnetic moment of the Dy3+ ions play a critical role in the structural evolution and enhanced properties of the BDFO films.
SURFACE & COATINGS TECHNOLOGY
(2022)
Article
Physics, Applied
Shaoqing Song, Longfei Jia, Shuolin Wang, Dahuai Zheng, Hongde Liu, Fang Bo, Yongfa Kong, Jingjun Xu
Summary: In this study, La and Co co-doped BiFeO3 (BLFCO) thin films were successfully fabricated, which exhibited excellent multiferroic properties and high ferroelectric polarization. These findings are significant for improving the performance of BFO multifunctional devices.
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2022)
Article
Materials Science, Multidisciplinary
Yeong Min Kwak, Kwang Lim Oh, Young Joon Ko, Sang Hyeok Park, Sangkyun Ryu, Mi Suk Kim, Kyu-Tae Lee, Minbaek Lee, Hyoungjeen Jeen, Jong Hoon Jung
Summary: This study investigated the magnetoresistance effect of epitaxial SRO films on a flexible CFO buffered mica substrate. The results showed that the magnetoresistance of the SRO films exhibited different characteristics at different temperatures and displayed consistent properties for orthogonal current directions with respect to the magnetic field.
CURRENT APPLIED PHYSICS
(2022)
Article
Chemistry, Multidisciplinary
Wan-Rong Geng, Yun-Long Tang, Yin-Lian Zhu, Yu-Jia Wang, Bo Wu, Li-Xin Yang, Yan-Peng Feng, Min-Jie Zou, Tong-Tong Shi, Yi Cao, Xiu-Liang Ma
Summary: This study demonstrates the existence of multi-field-driven magnetoelectric-optical coupling mediated by ferroelastic switching at room temperature. It provides a framework for designing potential multifunctional magnetoelectric devices.
ADVANCED MATERIALS
(2022)
Article
Materials Science, Ceramics
Jiaojiao Yi, Yining Zhai, Anlong Fan, Qi Gao, Lisha Liu
Summary: This study fabricated BiFeO3 thin films with an interfacial amorphous layer using chemical solution deposition, significantly enhancing the ferroelectric properties of the films. The conducting mechanisms of the films were investigated, providing insights into the impact of the designed interface. These results not only advance the potential use of BiFeO3 thin films in electronic devices but also promote the development of chemical solution deposition as a promising method.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2022)
Article
Chemistry, Physical
Zhiwei Chen, Haoyang Sun, Xiang Zhou, Hengli Duan, Wensheng Yan, Yuewei Yin, Xiaoguang Li
Summary: Room temperature electric field controlled magnetism shows great potential for designing low-power and high-speed spintronic devices. By using ferroelectric switching driven oxygen ion migration, the magnetic properties can be reversibly manipulated by tuning the ferroelectric polarization of the BiFeO3 layer.
JOURNAL OF MATERIOMICS
(2022)
Article
Materials Science, Ceramics
J. P. Liu, Z. L. Lv, Y. X. Hou, L. P. Zhang, J. P. Cao, H. W. Wang, W. B. Zhao, C. Zhang, Y. Bai, K. K. Meng, X. G. Xu, Jun Miao
Summary: Multi-element doping is an effective method to suppress leakage in BiFeO3 films. As the number of doping elements increases, the leakage current density of the BFO films decreases, and the conduction mechanism changes.
CERAMICS INTERNATIONAL
(2022)
Article
Energy & Fuels
Hyunwook Song, Jong Yeog Son
Summary: La-doped epitaxial BiFeO3 (LBFO) thin films with La doping concentrations ranging from 0 to 30 % were deposited on Nb-doped single-crystal SrTiO3 substrates using pulsed laser deposition. The LBFO thin films doped with 10 % La concentration exhibited the best ferroelectric properties due to a large c/a ratio of about 1.04. As the La concentration increased, the ferroelectric polarizations of the LBFO films decreased while the ferromagnetic properties improved steadily. Moreover, the LBFO thin films showed an increased energy storage efficiency with higher La concentrations, and the LBFO thin films with 30 % La doping concentration achieved a high energy storage density of about 30.7 J/cm3.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Multidisciplinary Sciences
Di Tian, Zhiwei Liu, Shengchun Shen, Zhuolu Li, Yu Zhou, Hongquan Liu, Hanghui Chen, Pu Yu
Summary: Berry curvature is crucial in exotic electronic states of quantum materials, and can be finely tuned by external stimuli. The study demonstrates the effective control of anomalous Hall resistivity in SrRuO3 thin films through epitaxial strain, providing insights into manipulating electronic states in quantum materials.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2021)
Article
Nanoscience & Nanotechnology
Mei Ying Liu, Jun Xi Yu, Xiao Li Zhu, Zhi Ping Bian, Xiang Zhou, Yu Hang Liang, Zhen Lin Luo, Yue Wei Yin, Jiang Yu Li, Xiang Ming Chen
Summary: In this study, h-Lu1-xInxFeO3 thin films were successfully prepared with a stable hexagonal structure achieved at room temperature. The films exhibited high remanent polarization and excellent polarization switching performance, along with a strong magnetoelectric coupling effect. These results demonstrate the potential application of h-Lu1-xInxFeO3 thin films in magnetoelectric memory and detection devices.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Nanoscience & Nanotechnology
Jun Zhang, Wuhong Xue, Tiancong Su, Huihui Ji, Guowei Zhou, Fengxian Jiang, Zhiyong Quan, Xiaohong Xu
Summary: The study focused on room-temperature multiferroic material GFO with ferrimagnetism, fabricating a thin film on a single-crystal substrate to demonstrate reversible and nonvolatile nanoscale magnetic domain reversal under purely electrical fields. The results showed a high potential for GFO thin film in next-generation magnetoelectric multifunctional devices.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Yuhan Liang, Dingsong Jiang, Yahong Chai, Yue Wang, Hetian Chen, Jing Ma, Pu Yu, Di Yi, Tianxiang Nan
Summary: In this study, we observed magnon spin transport through multiferroic BiFeO3 thin films in a spin pumping experiment at room temperature. The experimental results showed that the magnon spin transport efficiency is very high when the thickness of the BiFeO3 films exceeds 80 nm.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Yaoxin Zhang, Zhen Yu, Hao Qu, Shuai Guo, Jiachen Yang, Songlin Zhang, Lin Yang, Shaoan Cheng, John Wang, Swee Ching Tan
Summary: The emerging moisture-driven energy generation (MEG) technology has potential in fields like information security, but this potential is currently untapped. This study reports an original MEG structure that uses selective coating of ionic hygroscopic hydrogels on a carbon black surface to convert moisture energy. By combining hydrogel patterns and encoding methods, a humidity-regulated information encryption and display platform is developed, providing a hierarchical solution for high-security encryption and display.
ADVANCED MATERIALS
(2023)
Article
Engineering, Environmental
Jiangmin Jiang, Zhenghui Pan, Jiaren Yuan, Jun Shan, Chenglong Chen, Shaopeng Li, Yaxin Chen, Quanchao Zhuang, Zhicheng Ju, Hui Dou, Xiaogang Zhang, John Wang, John Wang
Summary: By constructing a stable and robust g-C3N4 protective layer on the surface of zinc metal anodes, the performance of aqueous zinc-ion batteries can be improved, inhibiting dendrite growth and enhancing Coulombic efficiency and lifespan.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Soren S. Sorensen, Xiangting Ren, Tao Du, Ayoub Traverson, Shibo Xi, Lars R. Jensen, Mathieu Bauchy, Satoshi Horike, John Wang, Morten M. Smedskjaer
Summary: This work demonstrates that water can depolymerize polyhedra with labile metal-ligand bonds in a cobalt-based coordination network, resulting in nonstoichiometric glasses. The addition of water molecules promotes the breakage of network bonds and coordination number changes, thereby lowering melting and glass transition temperatures. These structural changes alter the physical and chemical properties of the glass, similar to the concept of modifiers in oxides. This approach can be extended to other transition metal-based coordination networks, enabling diversification of hybrid glass chemistry.
Article
Materials Science, Multidisciplinary
Lei Jiang, Mengrui Lu, Piaoyun Yang, Yijing Fan, Hao Huang, Juan Xiong, Zhao Wang, Haoshuang Gu, John Wang
Summary: In this study, a pressure sensor matrix capable of two-dimensional pressure mapping was developed by using patterned piezoelectric (K,Na)NbO3 (KNN) nanorod arrays. The KNN nanorods exhibited excellent mechanical flexibility, elasticity, and piezoelectric performance, enabling a high sensitivity of up to 0.20 V N-1 and a detection limit as low as 20 g. The spatially separated micro sensor matrix allowed for accurate self-powered pressure mapping and precise analysis of mechanical stimulations.
SCIENCE CHINA-MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Tao Sun, Wenjie Zang, Jianguo Sun, Chenguang Li, Jun Fan, Enzhou Liu, John Wang
Summary: Non-carbon-supported single-atom electrocatalysts (SACs) have attracted great interest for water splitting due to their unique bond and coordination properties, as well as their superior and tunable catalytic performance compared to carbon-supported SACs and commercial catalysts. The structure, surficial chemical groups, vacancy defects of non-carbon host materials, as well as the properties and population of single atoms, play important roles in the electrocatalytic performance of these SACs. The wide range of host materials and single atom types present limitless possibilities for the design of SACs with tunable structures and electrocatalysis behaviors.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Polymer Science
Saeid M. Elkatlawy, Abdelhamid A. Sakr, John Wang, Abdelnaby M. Elshahawy
Summary: In this study, an effective strategy was designed to combine transition metal sulfides with nitrogen doped reduced graphene oxide hydrogels, improving the overall supercapattery properties.
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Hayden A. Evans, Dan Zhao, Pieremanuele Canepa, Anthony K. Cheetham, Dinesh Mullangi, Taner Yildirim, Yuxiang Wang, Zeyu Deng, Zhaoqiang Zhang, Thuc T. Mai, Fengxia Wei, John Wang, Angela R. Hight Walker, Craig M. Brown
Summary: The process of separating oxygen from air to create oxygen-enriched gas streams is important in both industrial and medical fields. However, existing technologies for this process are energy-intensive and require infrastructure. This study demonstrates that a metal-organic framework, Al(HCOO)3 (ALF), can effectively adsorb oxygen at near-ice temperatures, with good time-dependent selectivity. ALF exhibits a high oxygen adsorption capacity of approximately 1.7 mmol/g at 190K and atmospheric pressure, and approximately 0.3 mmol/g at salt-ice temperatures of 250K. ALF shows potential as a low-cost option for oxygen separation applications.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Zhaoqiang Zhang, Zeyu Deng, Hayden A. Evans, Dinesh Mullangi, Chengjun Kang, Shing Bo Peh, Yuxiang Wang, Craig M. Brown, John Wang, Pieremanuele Canepa, Anthony K. Cheetham, Dan Zhao
Summary: The exclusive capture of carbon dioxide (CO2) from hydrocarbon mixtures is crucial in the petrochemical industry. A new study introduces a ultramicroporous material, ALF, which can selectively capture CO2 from hydrocarbon mixtures with high capacity and efficiency. The material's unique pore chemistry allows for molecular recognition of CO2 by hydrogen bonding, while rejecting other hydrocarbons.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Physical
Hongfei Cheng, Jun Zhou, Huiqing Xie, Songlin Zhang, Jintao Zhang, Shengnan Sun, Ping Luo, Ming Lin, Shijie Wang, Zhenghui Pan, John Wang, Xian Jun Loh, Zhaolin Liu
Summary: Direct formic acid fuel cells (DFAFCs) are a promising energy source in the future low-carbon economy, but the lack of efficient electrocatalysts for anodic formic acid oxidation (FAO) hinders their scale-up and commercialization. The FAO performance of palladium hydrides (PdHx) has been found to be superior to pristine Pd, and this study explores the controlled synthesis and electrocatalytic behaviors of PdHx-based nanomaterials. The hydrogen intercalation-induced crystallization of PdNiP alloy nanoparticles is reported, and the obtained PdNiP-H nanoparticles exhibit excellent FAO performance, demonstrating their potential for DFAFC applications.
ADVANCED ENERGY MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Lu Mao, Xiaoyu Hao, Yu Zhang, Siew Yee Wong, Jiating He, Suxi Wang, Ximeng Liu, Xiaolei Huang, John Wang, Xu Li
Summary: In this study, hierarchical NiFe hydroxide-Cu arrays are prepared as the electrocatalysts for oxygen evolution reaction (OER) through solution etch and sequential electrolysis. The electrochemically reduced Cu nanoarrays serve as a conductive core, providing superior conductivity for electron transfer, while the unique hierarchical 3D structure offers a large active surface area, a short ion diffusion path, and open channels for efficient gas release. The resulting NiFe hydroxide-Cu arrays on copper foam exhibit outstanding catalytic performance with current densities of 10 and 100 mA cm(-2) achieved at 245 and 300 mV, respectively, in a 1 M KOH solution. Additionally, a small Tafel slope of 51 mV dec(-1) and excellent electrochemical durability of up to 100 h are demonstrated.
ACS APPLIED NANO MATERIALS
(2023)
Review
Materials Science, Multidisciplinary
Xianyang Zhang, Pengfei Chen, Siwuxie He, Bowen Jiang, Yong Wang, Yonghua Cheng, Jian Peng, Francis Verpoort, John Wang, Zongkui Kou
Summary: Biosensors featuring single molecule detection offer great opportunities in various fields, but face challenges due to the lack of activity, precision molecule selectivity, and understanding of the operating mechanism. Single-atom catalysts (SACs), particularly those that mimic the natural metalloenzyme structure, provide practical-use feasibilities for single molecule detections with high molecular selectivity and easy fabrication. This review discusses the history, advantages, and applications of SACs in molecule-scale biosensors, emphasizing their sensing modes and coordination-modulated signal amplifications.
Article
Chemistry, Multidisciplinary
Jianguo Sun, Binbin Liu, Qi Zhao, Chin Ho Kirk, John Wang
Summary: This article provides an overview of the research progress on MXenes in energy and catalysis, with a specific focus on the potential of termination-free MXene in catalysis and redox reactions. The authors believe that MX has great potential in future catalysis and propose the extension towards high entropy and single-atom modifications.
ADVANCED MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Yue Guo, Hanmei Jiang, Binbin Liu, Xingyang Wang, Yifu Zhang, Jianguo Sun, John Wang
Summary: Aqueous zinc-ion batteries (ZIBs) are considered promising for large-scale grid energy storage due to their safety, low costs, and environmental friendliness. Vanadium oxides, particularly V2O5, have been widely used as cathode materials for ZIBs because of their high theoretical capacity and structural stability. However, there are challenges in achieving high capacity, long lifespan, and excellent rate performance with vanadium-based ZIBs.
Article
Chemistry, Multidisciplinary
Weihao Liu, Jing Yang, Yizhe Zhao, Ximeng Liu, Jian Heng, Minghui Hong, Yong-Wei Zhang, John Wang
Summary: This study introduces a novel laser-ironing approach to modulate the structural and compositional evolution of electrocatalysts during the reaction, enhancing their performance and stability. The laser-ironing capping layer (LICL) formed during the process sustains the leaf-like morphology and promotes the formation of highly active Co3O4 nanoclusters. The results provide new insights into facile and high-precision surface microstructure control.
ADVANCED MATERIALS
(2023)
Review
Chemistry, Analytical
Xue Pan, Lu Bai, Chengcheng Pan, Zhicheng Liu, Seeram Ramakrishna
Summary: This review discusses the fabrication methods and applications of SERS substrates based on electrospun nanofibers, and highlights the challenges and prospects.
CRITICAL REVIEWS IN ANALYTICAL CHEMISTRY
(2023)
Article
Materials Science, Ceramics
Zilong Xiong, Wenzhuo Xue, Mujun Li, Feihu Tan, Yupeng Chen, Hongyu Yu
Summary: In this study, CBS glass/Al2O3 composites were developed for LTCC applications based on a CaO-B2O3-SiO2 (CBS) glass system with a high boron content. The study revealed that the softening of glass and interfacial reaction between the glass and Al2O3 were the two most important factors affecting LTCC's densification process. Real-time shrinkage rate of LTCC during sintering was successfully simulated, and it was proven that the formation of the CaAl2(BO3)O phase played a significant role in reducing glass viscosity and promoting dense structure formation. The resulting LTCC composite exhibited excellent performance for high-frequency applications.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Saurabh Kumar Sharma, Vinita Grover, Rakesh Shukla, Abid Hussain, Ambuj Mishra, Pawan Kumar Kulriya
Summary: In this study, the disordering caused by swift heavy ion irradiation in two different compositions of pyrochlore structures was investigated. X-ray diffraction, Raman spectroscopy, and high-resolution transmission electron microscopy were used to analyze the samples before and after irradiation. It was found that both compositions underwent amorphization due to irradiation, with a slower rate observed in Nd1.8Zr2.2O7.1. The irradiation-induced modified track region in Nd1.8Zr2.2O7.1 consisted of defect-rich pyrochlore structure, anion-deficient fluorite structure, and amorphous domains.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Jiabei He, Mengshan Song, Ming Yang, Miaomiao Zhu
Summary: This study investigates the influence of ion irradiation on high-entropy ceramics and finds that irradiation-induced lattice rearrangement can improve the radiation resistance of these ceramics.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Yajie Yu, Shi He, Zhengang Zhang, Haihua Chen, Peipeng Jin, Binnian Zhong, Linhui Zhang, Liping Wang, Cheng Lu
Summary: Silicide ceramics, including tantalum disilicide (TaSi2), are known for their exceptional physical properties but are limited in practical applications due to their inherent brittleness at room temperature. In this study, we successfully improved the mechanical properties of TaSi2 ceramics and increased their electrical conductivity by modifying the preparation methods and sintering conditions. These findings provide valuable insights for future applications of TaSi2 and the design of advanced ceramic materials.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Jian Li, Jia Liu, Yongcui Zhang, Wei Sun, Yang Wang, Haitao Wu, Ling Li, Chuanbing Cheng, Yingying Wang, Ke Tan, Futian Liu
Summary: Microstructure design plays a crucial role in regulating the microwave dielectric properties of materials, however, the understanding of frequency temperature stability and related micromechanism remains limited. In this study, a combination of first-principles calculations and experimental observation was used to investigate the correlation among sintering behavior, crystal structure, bonding nature, and microwave dielectric properties of LnPO(4) (Ln = Eu, Pr) ceramics. The research findings systematically clarify the optimized effect and micromechanism of lanthanides on the dielectric properties of monazite ceramics, providing insights into the design and enhancement of microwave dielectric materials.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Wenqian Pan, Xizhen Xia, Wei Zhou, Yang Li
Summary: The study investigates the frictional and wear behaviors of carbon fiber-reinforced SiC ceramic matrix composites with different fiber orientations mating with ceramic balls. The results show that fiber orientation significantly affects the friction and wear properties of the composites. Pads with randomly arranged fibers demonstrate better friction stability and lower wear volume, potentially suitable for bearing material applications. The research also explores the factors influencing the formation of continuous tribo-film and identifies abrasive wear and oxidation wear as the dominant wear mechanisms for the friction pairs.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Sergey Nikolaevich Perevislov, Ilya Evgenievich Arlashkin, Valentina Leonidovna Stolyarova
Summary: This paper describes the synthesis and sintering of MAX phases in the Zr-Al-C system. Different mixtures of initial Zr/Al/C and Zr/Al/ZrC powders were used to synthesize Zr2AlC and Zr3AlC2 MAX phases. The highest content of Zr3AlC2 MAX phase was obtained using a component ratio of 1:1.5:2-51.1 vol.% of Zr/Al/ZrC powders.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Weijia Luo, Xubin Wang, Baiheng Bai, Jianli Qiao, Xingcong Chen, Yongzheng Wen, Jingbo Sun, Lingxia Li, Ji Zhou
Summary: This study successfully establishes the relationship between internal strain and dielectric loss by synthesizing and designing specific structure of tungsten bronze ceramics, and concludes that controlling internal strain can effectively reduce dielectric loss. This research is of great significance for the development of future all-ceramic non-Hermitian devices.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Santanu Mondal, Juan Diego Shiraishi Lombard, Sreenivasulu Gollapudi, Carolina Tallon, Jie-Fang Li, Dwight Viehland
Summary: Ultrafast high-temperature sintering (UHS) is an effective method for rapidly densifying ZrB2 powders. The final grain size increases with longer sintering duration. X-ray diffraction and energy-dispersive spectroscopy show crystalline phase and compositional uniformity in ZrB2 after UHS.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
JiaNan Wang, ZhiQiang Li, YongZheng Zhu, Yao Liang, Yan Cui, HuaLong Tao, Bo Song, Alexander Nikiforov, ZhiHua Zhang
Summary: First-principles calculations were performed to investigate the crystal structure, electronic structure, and ion diffusion of sulfur-doped Li2FeSiO4. The results showed that sulfur doping can improve the electronic conductivity and reduce the energy barrier for ion diffusion.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Xiaodi Dai, Serdar Aydin, Mert Yuecel Yardimci, Gunter Reekmans, Peter Adriaensens, Geert De Schutter
Summary: This study investigates the rheological behavior, solidification process, and nanostructure changes of sodium hydroxide-activated slag (NH-AAS) and sodium silicate-activated slag (SS-AAS) pastes over time. The results show that NH-AAS and SS-AAS release similar heat and reach a similar reaction degree at their initial setting times, but have different gel structures.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Yanliang Ji, Simon Becker, Zichen Lu, Alexander Mezhov, Regine von Klitzing, Schmidt Wolfram, Dietmar Stephan
Summary: This study reveals the significant influence of resting time on the rheological properties of cement suspensions, which is closely related to non-absorbed polycarboxylate superplasticizers (PCEs) size variation. Adsorbed PCE during resting tends to bridge particles instead of dispersing them, leading to an increased yield stress.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Yifeng Huang, Xin Wang, Yinchang Ma, Xiang Lv, Jiagang Wu
Summary: This study investigates the effect of K/Na ratio on the phase structure, ferroelectric domains, and piezoelectric properties of potassium sodium niobate (KNN)-based ceramics. It reveals that high Na+ content leads to large ferroelectric domains, while high K+ content results in local polarity heterogeneity and distinct dielectric relaxational behavior. The balanced local polarity and stress heterogeneities contribute to improved piezoelectricity.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Zun Xia, Yedong Rong, Hao Li, Ye Dong, Hongbo Yu, Jie Xu, Xiuhui Wang, Jinlong Yang
Summary: This study presents the synthesis of hollow MgAl2O4 particles in situ within porous ceramics, resulting in volume expansion and the formation of a hierarchical pore structure, leading to a significant improvement in compressive strength.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Honglong Wang, Zhiguo Sun, Faming Xia, Chenguang Yang, Xiaoguang Wang, Jintang Li, Linxu Jiang
Summary: In this study, the micro-geometry morphology variation and microstructural transformation mechanism of muscovite crystals under electron beam irradiation were explored. The results revealed the instability of the muscovite lattice under irradiation, as well as the expansion and shrinkage of the lattice with increasing dose. The study also identified changes in chemical structure and other mechanisms involved. These findings are significant for the design of radiation-resistant silicate materials and the manufacturing of electronic components used in the aerospace industry.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)