4.3 Article

Evolution of High Coercivity in CoPt Nanoparticles Through Nitrogen Assisted Annealing

Journal

JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM
Volume 27, Issue 9, Pages 2123-2130

Publisher

SPRINGER
DOI: 10.1007/s10948-014-2564-6

Keywords

CoPt; Polyol process; Coercivity; Annealing; delta M

Funding

  1. Department of Science and Technology (DST), Govt. of India [SR/FST/PSI-117/2007]
  2. FAST track project [SR/FTP/ETA-11/2008]

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The presence of H (2) along with an inert gas during annealing was considered as a prerequisite in achieving high coercivity in alloys such as FePt and CoPt nanoparticles synthesized through chemical methods. CoPt nanoparticles were synthesized using a one-step polyol process without using any surfactant and annealed at various temperatures in N (2) atmosphere. The magnetic properties of Co Pt-40 (60) sample annealed at 700 C-o in N (2) atmosphere showed a room temperature coercivity of 8.4 kOe. The magnetic interactions present in the samples were studied using delta M measurements. The evolution of high coercivity in the samples annealed at 700 C-o showed that N (2) is a cheaper alternative to the existing reducing gas mixture.

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