Journal
JOURNAL OF STATISTICAL MECHANICS-THEORY AND EXPERIMENT
Volume -, Issue -, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/1742-5468/2010/02/P02009
Keywords
memory effects (theory); structural glasses (theory); stochastic processes (theory)
Categories
Funding
- Ministerio de Educacion y Ciencia (Spain) [FIS2008-01339]
- FEDER
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The Kovacs or crossover effect is one of the peculiar behaviours exhibited by glasses and other complex, slowly relaxing systems. Roughly it consists of the non-monotonic relaxation to its equilibrium value of a macroscopic property of a system evolving at constant temperature, when starting from a non-equilibrium state. Here, this effect is investigated for general systems whose dynamics is described by a master equation. To carry out a detailed analysis, the limit of small perturbations in which linear response theory applies is considered. It is shown that, under very general conditions, the observed experimental features of the Kovacs effect are recovered. The results are particularized for a very simple model, a two-level system with dynamical disorder. An explicit analytical expression for its non-monotonic relaxation function is obtained, showing a resonant-like behaviour when the dependence on the temperature is investigated.
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