Article
Materials Science, Ceramics
P. Amalthi, J. Judith Vijaya, L. John Kennedy, A. Mustafa, M. Bououdina, K. P. Shinde, D. H. Kim
Summary: Through the study of multicomponent perovskite nanomaterials, we found that the substitution of ions can affect the structure, magnetic and magnetocaloric properties of the materials. X-ray diffraction analysis confirmed the presence of a secondary cubic phase Nd2O3. The magnetocaloric effect was assessed through the magnetic-entropy change.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Multidisciplinary
Hsiang-Wei Tsai, Yen-Hsun Su
Summary: This study focused on enhancing the photocatalytic performance of catalysts for water-splitting reaction through surface plasmon resonance (SPR) effect and hetero-junction structure. Double perovskite LaFe(1-x)NixO(3) particles were synthesized and decorated with sea urchin-like Au nanoparticles (NPs). The hybrid structure showed improved photoelectrochemical hydrogen production efficiency, with the H-2 efficiency measured in ethanol significantly higher than in 1-butanol due to lower activation energies in the former solvent.
Article
Chemistry, Multidisciplinary
Kavish Kaup, Kevin Bishop, Abdeljalil Assoud, Jue Liu, Linda F. Nazar
Summary: A new fast ion-conducting lithium thioborate halide with perovskite topology and argyrodite-like lithium substructure has been reported, showing unprecedented lithium ion conductivity. Studies using single-crystal X-ray diffraction, neutron powder diffraction, and AIMD simulations elucidate the key factors influencing high lithium mobility.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Multidisciplinary
Jiafeng Zhang, Xiaoqing Jiang, Xiaotao Liu, Xin Guo, Can Li
Summary: This study reports the use of delta-FAPbI(3) to construct a yellow/black heterophase bilayer, which enhances the efficiency and stability of perovskite solar cells (PSCs). The delta-FAPbI(3) layer can effectively suppress charge recombination at the interface compared to the black-phase perovskite.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Arash Boochani, Moein Asshabi, Jabbar Khodadadi, Elmira Sartipi, Morteza Jamal, Jamshid Sabbagzadeh, Masoud Shahrokhi, Malieheh Amiri, Arash Yari, Shahram Solaymani, Amir hossein Sari, Saeid Jalali-Asadabadi
Summary: This work investigates the ground state stability of three Heuslerene Co2CrAl compounds (alpha, beta, and gamma phases) using density functional theory with different approximations. The results indicate that all three structures are stable and have different magnetic properties. The phonon branches of these compositions are positive, indicating complete dynamic stability under mechanical stresses and thermal vibrations. The electronic calculations show that Co2CrAl in bulk phase is a half-metal with 3 mu(B) magnetic moment and 100% spin polarization at the Fermi level. The electron density diagrams reveal the distribution of electron density on the surfaces of alpha and beta phases.
Article
Materials Science, Ceramics
Seungjoo Baek, In-Ho Jung
Summary: The phase diagram of the Y2O3-YF3 system up to 1973K was experimentally determined and confirmed using classical equilibration/quenching method and differential thermal analysis. The thermodynamic modeling of the system was done using CALPHAD method. The calculated metastable solubilities of YF3 in Y2O3 during plasma etching process were also presented.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2022)
Article
Physics, Fluids & Plasmas
Jozismar Rodrigues Alves, Vera Bohomoletz Henriques
Summary: The main focus of this paper is to address the question of thermodynamic stability in phase-separating systems at equilibrium. By introducing the thermodynamics of the interface between coexisting phases, the authors provide an alternative interpretation for the unstable regions observed in numerical simulations and restore the proper convexity of the true potentials. Additionally, they successfully calculate the surface tension in accordance with Onsager's analytic prediction.
Article
Chemistry, Physical
Lahoucine Atourki, Mouad Ouafi, Mohammed Makha, Bernabe Mari, Mohammed Regragui, Ahmed Ihlal, Mohammed Abd-lefdil, Miguel Mollar
Summary: This study investigated the direct effect of Li on the structural and optical properties of FAPbI(3) perovskite thin films, showing that a small amount of Li ions can significantly impact both the structure and optical properties by enhancing the formation of δ-FAPbI(3) instead of the desired α-FAPbI(3) phase. The presence of Li ions also resulted in a clear decrease in absorbance and PL intensity, indicating significant quenching and enhanced carrier extraction. Li ions were found to reduce non-radiative recombination and provide new insights for the development of high-stability and high-performance optoelectronic devices, particularly thin film perovskite solar cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Review
Chemistry, Physical
Yanmin Huang, Xiaojuan Lei, Tingwei He, Yuanzhi Jiang, Mingjian Yuan
Summary: Organic-inorganic hybrid perovskite materials have gained widespread attention in the field of photovoltaics, with stabilizing the alpha phase and achieving high-quality films being key for achieving high efficiency and long-term stability in perovskite photovoltaics. Methods to eliminate defects and improve carrier transport are crucial for high-performance photovoltaic devices.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
M. Ilatovskaia, O. Fabrichnaya
Summary: Phase relations in the Al2O3-MnOx system were investigated, showing that Al2MnO4 melts by peritectic reaction at 2000 K. A new thermodynamic description of the Al-Mn-O system was derived using experimental data and thermodynamic parameters were evaluated to describe experimental data in the entire compositional range.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Jinpeng Wang, Zhongbiao Li, Huaikuan Zang, Yanjun Sun, Yujun Zhao, Zhihao Wang, Zhiwen Zhu, Zhaoling Wei, Qiuju Zheng
Summary: The potential of BaZr0.1Fe0.9-xNixO3-delta as a cobalt-free and low-cost cathode for protonic ceramic fuel cells (PCFCs) was investigated. The study found that the material maintains a pure cubic perovskite structure within the doping concentration range of 15 to 20% and exhibits good chemical compatibility and high oxygen conductivity.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Multidisciplinary
Huifen Liu, Nengxu Li, Zehua Chen, Shuxia Tao, Chunlei Li, Lang Jiang, Xiuxiu Niu, Qi Chen, Feng Wang, Yu Zhang, Zijian Huang, Tinglu Song, Huanping Zhou
Summary: Phase instability is a major obstacle for the widespread application of formamidinium (FA)-dominated perovskite solar cells. This study investigates the reversible phase-transition process of FA(1-)(x)Cs(x)PbI(3) perovskite under humidity and the healing process of degraded devices. The findings provide a deepened understanding of the phase-transition process and offer an effective means to stabilize FA-dominated perovskites and devices for practical applications.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Physical
Xin Lv, Gaoyu Chen, Xia Zhu, Jiakun An, Jianchun Bao, Xiangxing Xu
Summary: In this work, the ternary halide perovskite phase diagram is constructed by the strategy of halide anion exchange between perovskite NCs. A two-phase perovskite NC system showing stable dual photoluminescence (PL) peaks is achieved.
Article
Chemistry, Physical
Xin Lv, Gaoyu Chen, Xia Zhu, Jiakun An, Jianchun Bao, Xiangxing Xu
Summary: The ternary halide perovskite phase diagram is constructed by the strategy of halide anion exchange between perovskite NCs, providing a method for regulating the composition and proportion of CsPbClaBrbI3-a-b. A stable two-phase perovskite NC system showing dual photoluminescence peaks has been achieved.
Article
Engineering, Civil
Jozsef Szilagyi
Summary: By considering isobaric and adiabatic wetting/drying cycles, it is possible to define the actual evaporation rate and three potential evaporation rates can be estimated by linking the temperature/vapor pressure coordinates of air and surface isenthalps. This method allows for accurate estimation of land evaporation rates with minimal input variables.
JOURNAL OF HYDROLOGY
(2021)
Article
Chemistry, Physical
A. R. Gilev, E. A. Kiselev, D. A. Malyshkin, K. S. Sukhanov, V. A. Cherepanov
Summary: The effect of air humidity on the transport properties of La(2-x)A(x)Ni(1-y)Fe(y)O(4)(+delta) oxides was studied, showing that the total conductivity decreased with increasing relative humidity, attributed to the hydration of the samples. The hydration affected the surface exchange process in LSNF0605, and water could participate in the surface exchange, suggesting the presence of proton conduction.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Inorganic & Nuclear
A. V. Bryuzgina, A. S. Urusova, V. A. Cherepanov
Summary: The phase diagram of the 1/zY(2)O(3)-1/zFe(2)O(3)-CoOx system has been experimentally studied and constructed in air at 1373 K. The stability boundaries of YFe1-xCoxO3 oxides with respect to Po-2 have been estimated for various temperatures within the range of 1173-1573 K. The results show that the limiting composition of the YFe1-xCoxO3 solid solution at 1373 K decreases linearly with decreasing x, reaching x=0 when the decomposition pressure of YFeO3 is equal to lg(Po-2/atm)=-13.3.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Materials Science, Ceramics
Tatiana Aksenova, Nadezhda E. Volkova, Antoine Maignan, Vladimir A. Cherepanov
Summary: The phase equilibria in the 1/2Nd(2)O(3)-BaO-1/2Fe(2)O(3) system were studied, and the crystal structure and oxygen content of different intermediate oxides were determined. The substitution of neodymium by barium was found to decrease the oxygen content and influence the thermal properties.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2022)
Article
Electrochemistry
A. R. Gilev, E. A. Kiselev, K. S. Sukhanov, D. V. Korona, V. A. Cherepanov
Summary: La2NiO4+delta, LCNF0604, LSNF0604, LSNF0605 and LSNF0504 compounds were synthesized by the citrate-nitrate technique and their phase purity was confirmed by X-ray powder diffraction. Electrochemical impedance spectroscopy studies showed that the polarization resistance decreased in the temperature range of 600-800 degrees C in wet air, with the order of LCNF0604>La2NiO4+delta>LSNF0504>LSNF0604>LSNF0605. The low frequency process was found to contribute significantly to the polarization resistance of the studied cells.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Inorganic & Nuclear
I. B. Golovachev, A. A. Trushnikov, N. E. Volkova, T. V. Aksenova, V. A. Cherepanov
Summary: The crystal structure and oxygen content of Ba(0.9)Ln(0.1)Fe(1 - y)Co(y)O(3 - delta) solid solutions were studied under different conditions. The unit cell parameter of the solid solutions increases with higher cobalt content or rare-earth atomic radius, while the oxygen content and mean oxidation state of metal ions decrease.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Physical
A. R. Gilev, E. A. Kiselev, M. E. Ozhiganov, V. A. Cherepanov
Summary: The polarization resistance of the studied electrodes increases with the number of perovskite layers, indicating slower ionic transport and increased oxygen dissociation.
SOLID STATE IONICS
(2022)
Article
Chemistry, Physical
Tatiana Aksenova, Darya K. Mysik, Vladimir A. Cherepanov
Summary: This study prepared a series of Gd1-xSrxCo1-yFeyO3-delta samples using a glycerol nitrate technique and investigated their structural and electrical properties. X-ray diffraction analysis revealed different crystal structures within different composition ranges, and thermogravimetric analysis was used to study the variation of oxygen content with temperature. Furthermore, measurements of relevant properties showed that Gd0.2Sr0.8Co0.3Fe0.7O3-delta exhibited the highest conductivity and predominantly p-type conductivity.
Article
Materials Science, Ceramics
K. S. Tolstov, N. E. Volkova, A. Yu Suntsov, I. L. Ivanov, L. Ya Gavrilova, V. A. Cherepanov
Summary: Anion-deficient perovskite-like Ba3SmFe2O7.5 was synthesized via a glycerol-nitrate method. High-temperature X-ray diffraction revealed a crystal structure transition temperature range of 800 and 840 ? and was confirmed by dilatometric analysis. The thermal expansion coefficient of Ba3SmFe2O7.5 was determined to be approximately 12.8 x 10(-6) K-1 between 25 ? and 800 ?. Magnetic experiments showed the high phase purity of the oxide and the presence of Fe3+ ions in high and intermediate spin states with a ratio of 75% and 25%, respectively.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Inorganic & Nuclear
A. V. Bryuzgina, A. S. Urusova, V. A. Cherepanov
Summary: A systematic study of the Y2O3 - BaO - Fe2O3 system near YBa2Fe3O8+8 reveals that the actual composition of the 123-type oxide differs from the ideal one. Single-phase oxide with a 123-type structure can be obtained at 1373 K in air only with a slight deficit of Ba and an excess of both Y and Fe components. The revised phase diagram for the Y2O3 - BaO - Fe2O3 system is constructed at 1373 K in air, including the composition of a previously unreported complex oxide.
JOURNAL OF SOLID STATE CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
I. A. Bastron, N. E. Volkova, A. Yu. Suntsov, V. A. Cherepanov
Summary: An excess of Dy in A-site was found to enable the synthesis of a single-phase perovskite-related oxide with the 123-type structure at 1100 degrees C in air. Cobalt ions fill the octahedrally coordinated positions, while iron and excess cobalt occupy pyramidal oxygen coordination. The oxygen content decreases with temperature, and a slight increase in thermal expansion slope is observed at temperatures above 200 degrees C. The electrical conductivity increases with temperature, reaching a maximum value at 900 degrees C. Magnetic measurements suggest the spin states of Fe3+ and Co2+, while Co3+ can have multiple states depending on coordination.
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
(2023)
Article
Chemistry, Physical
Artem R. Gilev, Evgeny A. Kiselev, Maksim E. Ozhiganov, Vladimir A. Cherepanov
Summary: This study analyzes the surface oxygen exchange in La2NiO4+a and La1.5Sr0.5Ni1-yFeyO4+a (y=0.3, 0.4) oxides. The results show that surface limitations occur in La2NiO4+a when the P(O2) gradient increases, and surface exchange plays a predominant role in the overall oxygen flux. The surface limitations in La2NiO4+a are attributed to a faster decrease in oxygen excess and Ni3+ concentration compared to La1.5Sr0.5Ni0.7Fe0.3O4+a and La1.5Sr0.5Ni0.6Fe0.4O4+a.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Physical
T. V. Aksenova, N. E. Volkova, V. S. Legonkova, V. A. Cherepanov
Summary: The homogeneity ranges and crystal structure of solid solutions with different compositions of Nd1-xBaxCo1-yFeyO3-delta were determined. Depending on the concentration of barium, the oxide can crystallize in different structures. The relationship between unit cell parameters and composition of the solid solutions was obtained. It was observed that the oxygen nonstoichiometry increased with the increase of barium and cobalt content.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
(2023)
Article
Materials Science, Multidisciplinary
A. S. Abramov, V. A. Safina, D. O. Alikin, D. Karpinsky, D. Zhaludkevich, V. Pryakhina, E. A. Kiselev, V. N. Shut, A. L. Zhaludkevich, V. Ya Shur, A. L. Kholkin
Summary: The morphotropic phase boundary (MPB) region of the BFO-BTO solid solution is investigated using comprehensive macroscopic and local methods, focusing on the synthesis conditions that affect the final phase composition and functional response. The difference in phase distribution and local switching behavior in two sets of BFO-BTO solid solutions prepared with different applied pressures is attributed to local chemical inhomogeneity caused by variations in solid-state sintering reactions. The more uniform mixing of polar and non-polar phases promotes the non-polar-to-polar phase transition and widens the MPB region.
Article
Chemistry, Inorganic & Nuclear
Caleb J. Bennett, Helen E. A. Brand, Alexander K. L. Yuen, Maria K. Nicholas, Brendan J. Kennedy
Summary: The temperature dependence of the crystal structure of Potassium Hexaiodoplatinate(IV) between 80 and 500 K is studied. Different crystal structures are observed at different temperatures, including monoclinic, tetragonal, and cubic structures. Accurate determination of the structures of K2PtI6 is important for further theoretical and practical research.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhuo Zeng, Jiangfu Zheng, Xiaoming Li, Changzheng Fan, Rongying Zeng, Wenqing Tang
Summary: An efficient method for phosphate removal from wastewater is urgently needed due to the environmental issue caused by excessive phosphorus. In this study, calcium aluminum layered double hydroxides (CaAl-LDHs) and six amino acid intercalated calcium aluminum layered double hydroxides (CaAl-amino acid-LDHs) were prepared and compared for their phosphate adsorption performance. L-Aspartic acid intercalated calcium aluminum layered double hydroxides (CaAl-Asp-LDHs) exhibited the highest phosphate adsorption capacity and faster removal rate compared to CaAl-LDHs. The phosphate adsorption mechanism on CaAl-Asp-LDHs involved electrostatic attraction, hydrogen bonds, complexation, and ion exchange. This environmentally friendly material shows promising potential for efficient phosphate removal from aquatic environments.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Rouzbeh Aghaei Hakkak, Thomas Schleid
Summary: The novel guanidinium hydro-closo-borates with [BnHn]2- (n = 10 and 12) anions were successfully synthesized via direct reaction. The crystal structures exhibit hydrogen bonding interactions and have the potential to facilitate H2 generation.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Liqiang Ma, Pengpeng Wei, Jingfang Li, Liye Liang, Guangming Li
Summary: A novel catalyst, H4PVMo2W9O40@rht-MOF-1, was developed using a one-pot hydrothermal method. It exhibited high efficiency and reusability in esterification reactions.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Liudmila A. Gorelova, Valentiva A. Yukhno, Maria G. Krzhizhanovskaya, Oleg S. Vereshchagin
Summary: Two new Ga-Ge disordered feldspar-related compounds were successfully synthesized using melt crystallization methods. Their stability and thermal expansion properties were studied under high-temperature conditions. The results showed that both compounds are stable within the studied temperature range and exhibit anisotropic thermal expansion.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Seifeddine Bdey, Nesrine Boussadoune, Francois Allard, Jacques Huot, Gabriel Antonius, Noura Fakhar Bourguiba, Pedro Nunez
Summary: The structure of a novel arsenate compound Na3Al3(AsO4)4 has been determined using X-ray diffraction. The crystal exhibits a monoclinic space group with suitable pathways for Na+ ion migration. The accuracy of the structural model was confirmed using various validation tools and density functional theory calculations.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Amit Kumar Atri, Ujwal Manhas, Sumit Singh, Irfan Qadir, Shikha Sharma, Preteek Sharma, Devinder Singh
Summary: This study synthesizes new oxygen deficient triple layered Ruddlesden-Popper (RP) phases via sol-gel method and investigates the effects of Cr3+ doping on their structural, optical, magnetic, and photocatalytic properties. The experimental results demonstrate that Cr3+ doping alters the interactions and leads to excellent photocatalytic performance in some phases.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Dat Le Thanh, Amandine Guiet, Emmanuelle Suard, Romain Berthelot
Summary: In this study, FeNb11O29 powder samples were prepared using a microwave-assisted solid-state synthesis method for the first time. The samples obtained rapidly from submicrometric oxide precursors showed enhanced cycling performance, possibly due to the easier ionic diffusion occurring in the smaller particles.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Raimund Ziegler, Felix R. S. Purtscher, Thomas S. Hofer, Gunter Heymann, Hubert Huppertz
Summary: We have successfully synthesized a new tellurium borate crystal under high-pressure and high-temperature conditions. The crystal structure and theoretical calculations have been thoroughly discussed.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Subhendu Jana, Eric A. Gabilondo, Paul A. Maggard
Summary: This study reports the synthesis and characterization of two previously unknown multinary selenides, Ba8Hf2Se11(Se-2) and Ba9Hf3Se14(Se-2), which display unique structures and optoelectronic properties competitive with existing perovskite-type chalcogenides.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Fei Ruan, Chonggui Lei, Fenglong Zhang, Jinxiao Bao, Fen Zhou, Min Xie, Pengfei Xu, Jianquan Gao
Summary: Studying the diffusion properties of hydrogen is important for designing new proton conductors. In the past, the chemical diffusion coefficient of hydrogen in proton conductors was usually obtained through a manual calculation method, resulting in difficulty in controlling the calculation accuracy. To address this issue, a mathematical algorithm and C language computer program were developed to calculate the chemical diffusion coefficient based on Fick's second law and Romberg numerical integral. The algorithm showed high precision and powerful computing function, and has the potential to replace the manual calculation method in calculating the chemical diffusion coefficient for hydrogen in proton conductors.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Deepika Shanubhogue, Suraj Mangavati, Ashok Rao, Ru-Ting Tsao, Yung-Kang Kuo
Summary: In this study, the effect of Y doping at the Sn-site on the structural, electrical, and low-temperature thermoelectric properties of the Cu2SnSe3 system is investigated. Y-doped compounds Cu2Sn1-xYxSe3 show reduced electrical resistivity, enhanced power factor, and decreased thermal conductivity, resulting in higher ZT values.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Wei Hong, Min Qing, Xun He, Lei Wang, Yu Pu, Qiyu Li, Zhimin He, Qin Dong, Rong Li, Xinglong Gou
Summary: This study developed a simple method to prepare SnS2 nanosheets and assembled them with MXene to form SnS2/MXene. The composite material exhibited abundant active sites, superior electron/ion transfer kinetics, and a unique 2D interlayer structure, resulting in high specific capacity, outstanding rate capability, and excellent cycling stability, with potential applications in LIBs.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Heng-Yu Ruan, Xue-Qian Wu, Tian-Yu Zhang, Yi Yuan, Le Wang, Ya-Pan Wu, Qing-Wen Han, Ruan Chi, Dong-Sheng Li
Summary: Two isostructural metalorganic frameworks (MOFs), CTGU-36-Co and CTGU-36-Ni, were synthesized, and CTGU-36-Ni demonstrated high activity as a molecular electrocatalyst for the methanol oxidation reaction.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Rachid Fakhreddine, Ali Ouasri, Abderrahim Aatiq
Summary: This paper reports the synthesis, structure, and spectroscopic studies of three novel metal orthophosphate salts. The structures of these compounds were refined using X-ray powder diffraction data. The infrared and Raman analysis revealed their symmetries and the UV-visible investigation determined their optical properties.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)