Journal
JOURNAL OF SOLID STATE CHEMISTRY
Volume 181, Issue 8, Pages 2087-2091Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2008.05.008
Keywords
crystal growth; crystal structure; oxide; nonlinear optical properties
Funding
- National Science Foundation [DMR-0312136, DMR-0604454]
- Department of Energy, BES-Chemical Sciences, Geosciences, and Biosciences Division [DE-FG0203ER15457]
- Materials Research Center of Northwestern University [DMR-0520513]
- West Light Foundation of the Chinese Academy of Sciences
- Welch Foundation
- NSF [DMR 0652150]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1005827] Funding Source: National Science Foundation
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Bi2Cu5B4O14 crystallizes in the noncentrosymmetric triclinic space group P1 (No. 1) with cell parameters a = 10.1381(11)angstrom, b = 9.3917(11)angstrom, c = 3.4566(4)angstrom, alpha = 105.570(2)(-), beta = 92.275(2)(-), gamma = 107.783(2), Z = 1 and R-1 = 0.0401 and w/R-2 = 0.0980. It is a layered structure that is built up from sheets of rectangular CuO4 and trigonal BO3 groups. The sheets are connected by infinite chains of edge shared BiO6 polyhedra that intersect the bc plane at an angle slightly greater than 90 degrees C. The Second-harmonic generation efficiency of Bi2Cu5B4O14, using 1064 nm radiation, is about one half times that of KH2PO4. (C) 2008 Elsevier Inc. All rights reserved.
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