Review
Chemistry, Analytical
Polina S. Fomina, Mikhail A. Proskurnin, Boris Mizaikoff, Dmitry S. Volkov
Summary: This review discusses the analytical capabilities of Fourier-transform infrared spectroscopic techniques for analyzing aqueous solutions and provides examples.
CRITICAL REVIEWS IN ANALYTICAL CHEMISTRY
(2023)
Article
Engineering, Environmental
Jianchao Wang, Dongbei Yue, Mingchun Li, Huijing Wang, Jianbing Wang, Chunrong Wang, Huijiao Wang
Summary: This study evaluated the application of carbon nitride nanosheets (CN-Ns) for adsorption of humic substances and leachate nanofiltration concentrates. The results showed that increasing the thermal oxidation temperature improved the adsorption performance of CN-Ns and their affinity for humic substances. This finding is important for the treatment of landfill leachate.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Agronomy
Evgeniya A. Karpukhina, Dmitry S. Volkov, Mikhail A. Proskurnin
Summary: The existing techniques for lignosulfonate in humate fertilizers lack selectivity and require labor- and time-consuming sample preparation. This study developed a procedure based on ATR FTIR spectroscopy with simple sample preparation for directly quantifying lignosulfonates in aqueous solutions. The technique shows potential for analyzing fertilizers of simple composition and quality control of pure humates used for plant growth.
Article
Chemistry, Multidisciplinary
Chenchen Wu, Xiangdong Guo, Yu Duan, Wei Lyu, Hai Hu, Debo Hu, Ke Chen, Zhipei Sun, Teng Gao, Xiaoxia Yang, Qing Dai
Summary: In this study, a tunable infrared transparent microfluidic system with graphene plasmons was developed to identify nanoscale proteins. By adjusting the system's transparency, the infrared absorption of water was eliminated, allowing for accurate measurements of the proteins. This study provides a new platform for studying biological processes.
ADVANCED MATERIALS
(2022)
Article
Environmental Sciences
Tamiris Conceicao de Aguiar, Danielle Franca de Oliveira Torchia, Tadeu Augusto van Tol de Castro, Orlando Carlos Huertas Tavares, Samuel de Abreu Lopes, Lucas de Souza da Silva, Rosane Nora Castro, Ricardo Luiz Louro Berbara, Marcos Gervasio Pereira, Andres Calderin Garcia
Summary: This study evaluated the structural patterns of 80 humic acid samples from different soils using spectroscopic characterization and chemometric techniques. Despite their different sources, all samples had similar structural patterns, but different relative quantities of organic C species. The humification process depends on the characteristics of the soil and the local environment. The structural patterns justify the existence of humic substances with self-assembled, hydrophilic, and hydrophobic domains that can undergo transformations under certain conditions, altering the balance of organic carbon in the environment.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Agronomy
Konstantin Korsakov, Alexey Stepanov, Lev Pozdnyakov, Olga Yakimenko
Summary: The effects of three types of urea fertilizers on soil N transformation processes were examined in a laboratory experiment. It was found that humate-coated urea (U_HA) showed advantages in reducing N losses, increasing N-NH4 content, and decreasing N2O emissions compared to conventional urea. U_HA also promoted soil respiration and microbial activity, making it a promising tool for reducing N losses in soils.
Article
Environmental Sciences
Francielly Torres Dos Santos, Cleide Fehmberger, Cleiton Margatto Aloisio, Ivonete Rossi Bautitz, Eliane Hermes
Summary: Adding crude glycerin during composting of organic swine waste can increase temperature and mineralization of organic matter, promoting stabilization of organic compost. The organic composts have high nutrient contents and are non-toxic, making them suitable for agricultural use.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Agronomy
Michal Dudek, Beata Labaz, Magdalena Bednik, Agnieszka Medynska-Juraszek
Summary: Unfavorable changes in both quantity and quality of soil organic matter are caused by degradation processes, such as water erosion resulting from intensive agricultural activities. It is therefore urgent to identify appropriate indicators for soil quality or degradation. This study investigated the use of humic and fulvic fractions in determining the processes of soil formation and degradation rates in chernozemic soils. The results showed that the HA/FA ratio was higher in non-eroded and accumulative soils compared to eroded or forest soils, indicating a potential relationship between land usage and degradation rate.
Article
Engineering, Environmental
C. F. Martins, L. A. Neves, R. Chagas, L. M. Ferreira, C. A. M. Afonso, I. M. Coelhoso, J. G. Crespo, J. PB. Mota
Summary: This study investigates the absorption of carbon dioxide (CO2) by ionic liquids (ILs) with quaternary ammonium cations combined with biocompatible anions from renewable sources. The research combines theoretical modeling and experimental analysis to understand the absorption characteristics and dynamics. Experimental validation of the proposed model provides insights for designing new absorption processes for CO2 capture.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Agronomy
Maria Roulia, Alexandros A. Vassiliadis
Summary: This study investigated the interactions of dye C.I. Basic Blue 3 with potassium humate in aqueous systems. It found that the adsorption of dye is influenced by pH and temperature, with a significant increase in dye adsorption observed under mildly acidic conditions. Various adsorption models were fitted to the experimental data, and thermodynamic quantities were calculated to analyze the adsorption process.
Article
Agronomy
Dmitry S. Volkov, Olga B. Rogova, Mikhail A. Proskurnin
Summary: This study explored the use of temperature-monitored IR spectroscopy to study the organic and mineral composition of humic substances. The analysis revealed characteristic bands and changes in band positions and intensities, allowing for a detailed understanding of the structure of humic substances.
Article
Biochemistry & Molecular Biology
Amber R. Titus, Pedro P. Madeira, Luisa A. Ferreira, Alexander Belgovskiy, Elizabeth K. Mann, Jay Adin Mann, William Meyer, Anthony E. Smart, Vladimir N. Uversky, Boris Y. Zaslavsky
Summary: This study provides the first evidence that dissolved globular proteins can alter the arrangement of hydrogen bonds in water, with different proteins having quantitatively different effects. Through spectroscopic analysis and nuclear magnetic resonance techniques, the researchers found strong correlations between solvent acidity and hydrogen bond arrangement in aqueous solutions.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Multidisciplinary Sciences
Rosario Javier-Astete, Jessenia Melo, Jorge Jimenez-Davalos, Gaston Zolla
Summary: This study validated a model for the classification of wood species and a universal model for the rapid determination of cellulose, hemicellulose, and lignin using FTIR spectroscopy coupled with chemometrics. The results showed that the full spectra can be used to differentiate different species and identify infrared peaks associated with cellulose, hemicellulose, and lignin. In addition, the full spectra helped build a three species universal model for quantifying the principal wood chemical components. Therefore, the study demonstrated that FTIR-ATR, together with chemometrics, is a reliable method for discriminating wood species and determining wood chemical composition.
SCIENTIFIC REPORTS
(2023)
Article
Agronomy
Mikhail A. Proskurnin, Dmitry S. Volkov, Olga B. Rogova
Summary: Diffuse reflectance FTIR measurements with 2D-COS were used to accurately identify the bands of chernozem soil organic matter (SOM) and mineral silicate matrix. The study compared samples from different land use types of a long-term field experiment. Homospectral and synchronous 2D-COS maps revealed correlation regions related to hydrogen bonds, SOM, and quartz matrix. The SOM range had distinct signatures, distinguishing different land use pairs. Asynchronous 2D-COS maps showed bands related to the proportion of silicate to quartz in small fractions, as well as carbonyl, carboxylate, and aromatic C-C in larger factions. The proposed approach provides reliable identification of SOM components with weaker IR bands compared to the mineral matrix.
Article
Chemistry, Multidisciplinary
Xiongxin Peng, Shuang Gai, Kui Cheng, Fan Yang
Summary: The study conducted hydrothermal humification kinetics experiments using corn straw as raw material and employed characterization techniques such as ultra-performance liquid chromatography, nuclear magnetic resonance spectroscopy, and Fourier-transform ion cyclotron resonance mass spectrometry to determine the formation mechanism of artificial humic substances (A-HS). The results showed that in an alkaline environment, rapid dissociation of lignocellulose can occur, with cellulose and hemicellulose being hydrolyzed into glucose and xylose, further dehydrated to form 5-hydroxy furfural and furfural, and then rehydrated to synthesize levulinic acid and other small molecular acids. These small precursors then combine with lignin fragments to form fulvic acids, humic acids, and even humin. The proposed mechanism of hydrothermal humification is of great significance for the design, synthesis, and application of A-HS in sustainable agriculture.
Review
Chemistry, Analytical
Polina S. Fomina, Mikhail A. Proskurnin, Boris Mizaikoff, Dmitry S. Volkov
Summary: This review discusses the analytical capabilities of Fourier-transform infrared spectroscopic techniques for analyzing aqueous solutions and provides examples.
CRITICAL REVIEWS IN ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Physical
Maria G. Chernysheva, Ivan S. Chaschin, Gennadii A. Badun, Viktor G. Vasil'ev, Ivan V. Mikheev, Tianyi Shen, Maria A. Sinolits, Natalia P. Bakuleva
Summary: Nanodiamond adsorption coatings can enhance the mechanical properties of collagen tissue. Negatively charged nanodiamonds have a stronger impact on the mechanical characteristics. A graphene layer can prevent tissue calcification. Nanodiamond and chitosan films significantly enhance the mechanical properties of bovine pericardium.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Chemistry, Physical
Anna S. Semenkova, Anna Yu. Romanchuk, Irina F. Seregina, Ivan Mikheev, Valentina S. Svitelman, Stepan N. Kalmykov
Summary: The present study investigated the sorption behavior of Eu(III) on kaolinite, focusing on two kaolinite samples with different origins and compositions. A high-purity natural sample of kaolinite was used to examine the dependence of sorption on ionic strength, pH, and radionuclide concentrations, and compared with another kaolinite sample containing admixtures of other clay minerals. The study also observed the effect of cations leaching from clay on the sorption. Based on experimental results, a thermodynamic sorption model of Eu(III) sorption onto kaolinite was developed, taking into account ion-exchange, surface complexation reaction, and competition with Al3+ sorption. The model was successfully tested on literature data for other kaolinite samples.
APPLIED CLAY SCIENCE
(2023)
Article
Materials Science, Ceramics
Polina A. Krokhicheva, Margarita A. Goldberg, Alexander S. Fomin, Dinara R. Khayrutdinova, Olga S. Antonova, Alexander S. Baikin, Anatoliy A. Konovalov, Aleksander V. Leonov, Ivan V. Mikheev, Ekaterina M. Merzlyak, Valentina A. Kirsanova, Irina K. Sviridova, Natalia S. Sergeeva, Sergey M. Barinov, Vladimir S. Komlev
Summary: This study aims to develop magnesium calcium phosphate bone cements (MCPCs) with antibacterial properties by incorporating silver ions. Increasing the silver ion concentration significantly improved the mechanical properties of the cements (compressive strength reached 41 +/- 2 MPa) and exhibited an 8 mm inhibition zone against Escherichia coli and Staphylococcus aureus in a disk diffusion test, without toxicity to MG-63 cells in vitro. Analysis of the MCPC samples soaked in Kokubo's simulated body fluid showed the formation of merrillite phase on the surface, transforming into bobierrite phase after 28 days of soaking. Histological examination and micro-CT analysis confirmed the osteoconductive and biodegradable nature of the newly developed MCPCs, making them suitable as bone substitutes.
CERAMICS INTERNATIONAL
(2023)
Article
Biochemistry & Molecular Biology
Mikhail A. Proskurnin, Elena V. Proskurnina, Viktoriya R. Galimova, Andrei V. Alekseev, Ivan V. Mikheev, Yuri A. Vladimirov
Summary: Thermal lens spectrometry and spectrophotometric titration were used to analyze the composition and solubility of the complex of oxidized cytochrome c with cardiolipin. Thermal lens spectrometry measured the solubility of the complex at nanomolar concentrations, while spectrophotometric titration assessed the soluble fraction of the complex at micromolar concentrations.
Article
Biochemistry & Molecular Biology
Daria-Maria V. Ratova, Ivan V. Mikheev, Grigoryi R. Chermashentsev, Konstantin I. Maslakov, Sergei Yu. Kottsov, Dmitrii N. Stolbov, Sergey V. Maksimov, Madina M. Sozarukova, Elena V. Proskurnina, Mikhail A. Proskurnin
Summary: This paper proposes a fast method for preparing aqueous graphene oxide dispersions by electrochemical oxidation of a graphite anode without preliminary intercalation with oxidizing agents. Ultrasonic probing in the modulation mode of ultrasonic waves (work/rest) was used for more efficient graphite oxidation-exfoliation. It is shown that the 4/2 s mode of ultrasonic modulation is the most effective in terms of probe material's low corrosion, maintaining optimum synthesis temperature, and achieving the best characteristics of the resulting product.
Article
Chemistry, Multidisciplinary
Vladislav R. Khabibullin, Liliya O. Usoltseva, Ivan V. Mikheev, Mikhail A. Proskurnin
Summary: The growing interest in heat-conducting nanofluids requires highly sensitive methods for analyzing the thermal properties. Thermal lens spectrometry (TLS) lacks a general approach for measuring and interpreting results for dispersed systems. This study justifies the selection of measurement parameters for nanofluids of silicon oxide in water and substantiates the interpretation of thermal diffusivity measurements. It is possible to detect and distinguish thermal effects with high accuracy using the TLS approach.
Article
Agronomy
Evgeniya A. Karpukhina, Dmitry S. Volkov, Mikhail A. Proskurnin
Summary: The existing techniques for lignosulfonate in humate fertilizers lack selectivity and require labor- and time-consuming sample preparation. This study developed a procedure based on ATR FTIR spectroscopy with simple sample preparation for directly quantifying lignosulfonates in aqueous solutions. The technique shows potential for analyzing fertilizers of simple composition and quality control of pure humates used for plant growth.
Article
Environmental Sciences
Nikita A. Sobolev, Konstantin S. Larionov, Darya S. Mryasova, Anna N. Khreptugova, Alexander B. Volikov, Andrey I. Konstantinov, Dmitry S. Volkov, Irina V. Perminova
Summary: Pollution of the Arctic Ocean by potentially toxic elements (PTEs) is a current environmental problem. Humic acids (HAs) play an important role in the regulation of PTE mobility in soil and water. The thawing of permafrost could increase the mobility of PTEs in the Arctic Ocean due to the release of organic matter with a specific molecular composition. The adsorption experiments have shown that peat and alas HAs have a higher affinity for binding both Cu2+ and Ni2+ ions compared to Yedoma HAs.
Article
Chemistry, Inorganic & Nuclear
Ivan V. Mikheev, Viktor A. Verkhovskii, Sofiya M. Byvsheva, Dmitry S. Volkov, Mikhail A. Proskurnin, Vladimir K. Ivanov
Summary: Excitation-emission matrix (EEM) fluorescence spectroscopy was used to quantify unmodified fullerenes C-60 and C-70 in different solvents at room temperature. The fluorescence intensity and parameters depend on the fullerene and solvent, allowing for quantification of mixtures without separation. The method was successfully applied to model and real mixtures of C-60 and C-70, with detection limits of 7 nmol/L and 2 nmol/L, respectively.
Article
Thermodynamics
Ekaterina Belova, Julia D. Shakirova, Konstantin A. Lyssenko, Ivan Mikheev, Alexey S. Maliutin, Nikita A. Kovalenko, Irina A. Uspenskaya
Summary: Solid-liquid equilibria in the Ni(CH3SO3)(2)-H2O, Co(CH3SO3)(2)-H2O, and Mn(CH3SO3)(2)-H2O systems were investigated using isothermal solubility and DSC methods. TG and X-Ray diffraction were employed to identify solid phases in equilibrium with the solution. The vapor pressure of water was determined at different temperatures in the Ni(CH3SO3)(2)-H2O, Co(CH3SO3)(2)-H2O, and Mn(CH3SO3)(2)-H2O systems. Parameters of the Pitzer-Simonson-Clegg model were obtained based on vapor-liquid (VLE) and solid-liquid (SLE) equilibria data. The stability parameters of hydrates in these systems were estimated and binary phase diagram fragments were calculated.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2023)
Article
Chemistry, Multidisciplinary
Vladislav R. R. Khabibullin, Daria-Maria V. Ratova, Dmitrii N. N. Stolbov, Ivan V. V. Mikheev, Mikhail A. A. Proskurnin
Summary: The applicability of thermal lens spectrometry in measuring thermal diffusivity in complex systems was studied, and a mathematical method was proposed to indicate a systematic error within 1%. The thermal properties of graphene oxide dispersions were investigated, and it was found that the thermal diffusivity reaches a minimum with increasing concentration, which can be utilized for thermal insulation. Additionally, extended laser irradiation led to a change in thermal diffusivity, indicating photochemical reduction of graphene oxide.
Article
Materials Science, Biomaterials
Madina M. Sozarukova, Ekaterina M. Kochneva, Elena V. Proskurnina, Ivan V. Mikheev, Dmitry O. Novikov, Mikhail A. Proskurnin, Vladimir K. Ivanov
Summary: This study investigates the interaction between nanoscale CeO2 and human serum albumin (HSA), finding that the presence of nanoparticles can alter the structure of albumin without affecting its function.
ACS BIOMATERIALS SCIENCE & ENGINEERING
(2023)