4.5 Article

The effect of polymer-induced attraction on dynamical arrests of polymer composites with bimodal particle size distributions

Journal

JOURNAL OF RHEOLOGY
Volume 57, Issue 6, Pages 1669-1691

Publisher

JOURNAL RHEOLOGY AMER INST PHYSICS
DOI: 10.1122/1.4822254

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Funding

  1. U.S. Department of Energy, Division of Materials Science through the Frederick Seitz Materials Research Laboratory at the University of Illinois Urbana-Champaign [DE-FG02-07ER46471]
  2. U.S. Department of Energy [DE-FG02-07ER46471, DE-FG02-07ER46453]

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We explore the flow properties of nanocomposite melts where the particles have bimodal size distributions and experience a weak attraction produced by suspending silica particles in polyethylene glycol melts with a molecular weight of 2000 (PEG2000). The polymer is unentangled and adsorbs to the particle surface. The volume fraction ratio of large particles to total particle volume fraction, R, is systematically varied to study the effects of this polymer-induced attraction on suspension rheology. The maximum volume fraction, phi(m), of the particles varies in a nonmonotonic manner of R as demonstrated in studies of the same mixtures when suspended in polyethylene glycol with a molecular weight of 400 (PEG400), where the particles experience excluded volume interactions. The dynamical arrest volume fraction phi(x), of nanocomposite melts in PEG2000 monotonically increases with R. In frequency sweep experiments, the plateau elastic modulus is dominated by attractive interactions and increases with the total particle volume fraction, phi(c), proportionally with 1/(h(2) < D >), where < D > is the volume average particle diameter and h is the average particle-particle surface separation. As R is varied, this universal yielding behavior occurs at constant surface separation, h, suggesting that the flow properties of the mixtures can be understood as being equivalent to flow properties of homogeneous particle suspensions experiencing short-range attractions with an extent independent of particle size. (C) 2013 The Society of Rheology.

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