Journal
JOURNAL OF RAMAN SPECTROSCOPY
Volume 41, Issue 6, Pages 678-683Publisher
WILEY
DOI: 10.1002/jrs.2499
Keywords
in situ Raman spectra; low-density amorphous ice; high-density amorphous ice; temperature-induced transition
Categories
Funding
- NASA-PGG
- NASA-NAI
- NSF-DMR
- NSF-EAR
- DOE (NNSA) through CDAC
Ask authors/readers for more resources
The transformation of low-density amorphous (LDA) ice produced from high-density amorphous (HDA) ice was studied up to 400 MPa as a function of temperature by in situ Raman spectroscopy and optical microscopy. Changes in these amorphous states of H2O were directly tracked without using emulsions to just above the crystallization temperature T-x. The spectra show significant changes occurring above similar to 125 K. The results are compared with data reported for the relaxation behavior of HDA, to form what we call relaxed HDA, or rHDA. We find a close connection with expanded HDA (eHDA), which is reported to exist as another metastable form in this P-T region. The observation of this temperature-induced LDA transition under pressure complements the previously observed pressure-induced reversible transition between LDA and HDA at 120-140 K. Copyright (C) 2009 John Wiley & Sons, Ltd.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available