4.5 Article

Effective uranium biosorption by macrofungus (Russula sanguinea) from aqueous solution: equilibrium, thermodynamic and kinetic studies

Journal

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
Volume 317, Issue 3, Pages 1387-1397

Publisher

SPRINGER
DOI: 10.1007/s10967-018-6039-2

Keywords

Macrofungus; Russula sanguinea; Biosorption; Uranium; Thermodynamics and kinetics

Funding

  1. Unit of the Scientific Research Projects of Cumhuriyet University
  2. Gaziosmanpasa University
  3. Karadeniz Technical University
  4. King Fahd University of Petroleum and Minerals
  5. Turkish Academy of Sciences

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Russula sanguinea (R. sanguninea) macrofungus was employed as a novel cost-effective biosorbent for efficient removal of U(VI) ions from aqueous solution. FT-IR spectroscopy and SEM/EDS technique were used for morphological and chemical characterizations. The maximum adsorption capacity of the macrofungus was found as 174.3 mg/g at pH 5 and 20 A degrees C. The kinetic data best fit with the pseudo-second-order kinetic model (r (2) > 0.99 for the studied temperatures). The exothermic and spontaneous nature of the biosorption process was confirmed by the thermodynamic findings. The reusability test demonstrated that the macrofungus had a good sorption/desorption performance.

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