Journal
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
Volume 298, Issue 3, Pages 2057-2063Publisher
SPRINGER
DOI: 10.1007/s10967-013-2641-5
Keywords
Uranium extraction; TiO-PAN; NaTiO-PAN; Fresh water; Titanium dioxide; Sodium titanate
Funding
- Ministry of Industry and Trade of the Czech Republic [FR-TI3/245]
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Possibility of uranium extraction on titanium oxide (TiO)-polyacrylonitrile (PAN) and sodium titanate (NaTiO)-PAN composite absorbers prepared from hydrated TiO and NaTiO embedded into a matrix of PAN binder was studied. Both TiO-PAN and NaTiO-PAN absorbers might be advantageous for repeated extraction of uranium from fresh water. Appropriate flow rates were found up to 60 BV h(-1) for both the absorbers. Elution of uranium and regeneration of both the absorbers may be accomplished by hydrochloric acid solutions of concentration 0.1 mol L-1 and more. Practical sorption capacity (up to 10 % break-through) from tap water containing 2.3 mu g U mL(-1) was similar to 4.6 and similar to 1.5 mg of uranium per 1 mL of swollen TiO-PAN and NaTiO-PAN absorber, respectively.
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