Journal
JOURNAL OF POWER SOURCES
Volume 245, Issue -, Pages 678-683Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2013.06.158
Keywords
Li-ion battery; In operando studies; Fatigue effect; Spatial lithium distribution; Neutron powder diffraction; Neutron radiography and tomography
Funding
- Deutsche Forschungsgemeinschaft (Research Collaborative Centre 595 Electrical Fatigue in Functional Materials)
Ask authors/readers for more resources
Spatially-resolved neutron diffraction has been applied to probe the lithium distribution in radial direction of a commercial Li-ion cell of 18650-type. The spatial evolution of selected Bragg reflections for LiCoO2 (positive electrode, cathode) and graphite and lithium intercalated graphite (negative electrode, anode) was observed and evaluated by taking beam attenuation and cell geometry effects into account. No evidences for lithium inhomogeneities have been found for the investigated set of cells. Computed neutron tomography using a monochromatic neutron beam confirmed the homogeneous lithium distribution. The relevance of the monochromatic beam to neutron imaging studies of Li-ion cells is discussed. (C) 2013 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available