4.8 Article

Contribution of oxygen partial density of state on lithium intercalation/de-intercalation process in LixNi0.5Mn1.5O4 spinel oxides

Journal

JOURNAL OF POWER SOURCES
Volume 244, Issue -, Pages 544-547

Publisher

ELSEVIER
DOI: 10.1016/j.jpowsour.2013.01.189

Keywords

High voltage spinel oxide; X-ray absorption fine structure; X-ray absorption near-edge structure; Lithium-ion battery

Ask authors/readers for more resources

The electronic structural changes during lithium-ion intercalation/de-intercalation process of nickel substituted lithium manganese spinet oxides have been investigated by using X-ray absorption near-edge structure (XANES) spectra of O K-edges as well as Ni L-3-edges and Mn L-3-edges. The results of the XANES spectra indicate that the electronic structure of both manganese and oxygen atoms contribute on the redox reaction at 0.06 <= x < 1, and only that of nickel atom affect the redox reaction at 1 < x <= 1.78 in LixNi0.5Mn1.5O4. Thus, the electronic structural change of oxygen atom is also crucial for considering redox reaction at intercalation/de-intercalation process, and the contribution of the oxygen atom on redox reaction differs in various redox cation species. (C) 2013 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

Analytical Measurements to Elucidate Structural Behavior of 2,5-Dimethoxy-1,4-benzoquinone During Charge and Discharge

Hikaru Sano, Nobuhiko Takeichi, Minami Kato, Masahiro Shikano, Tetsu Kiyobayashi, Hajime Matsumoto, Susumu Kuwabata, Masaru Yao

CHEMSUSCHEM (2020)

Article Chemistry, Physical

3D Operando Imaging and Quantification of Inhomogeneous Electrochemical Reactions in Composite Battery Electrodes

Yuta Kimura, Aina Tomura, Mahunnop Fakkao, Takashi Nakamura, Nozomu Ishiguro, Oki Sekizawa, Kiyofumi Nitta, Tomoya Uruga, Toyoki Okumura, Mizuki Tada, Yoshiharu Uchimoto, Koji Amezawa

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2020)

Article Energy & Fuels

A Potential Cathode Material for Rechargeable Potassium-Ion Batteries Inducing Manganese Cation and Oxygen Anion Redox Chemistry: Potassium-Deficient K0.4Fe0.5Mn0.5O2

Titus Masese, Kazuki Yoshii, Kohei Tada, Minami Kato, Satoshi Uchida, Keigo Kubota, Toshiaki Ina, Toyoki Okumura, Zhen-Dong Huang, Junya Furutani, Yuki Orikasa, Hiroshi Senoh, Shingo Tanaka, Masahiro Shikano

ENERGY TECHNOLOGY (2020)

Article Chemistry, Physical

Influence of Active Material Loading on Electrochemical Reactions in Composite Solid-State Battery Electrodes Revealed by Operando 3D CT-XANES Imaging

Yuta Kimura, Mahunnop Fakkao, Takashi Nakamura, Toyoki Okumura, Nozomu Ishiguro, Oki Sekizawa, Kiyofumi Nitta, Tomoya Uruga, Mizuki Tada, Yoshiharu Uchimoto, Koji Amezawa

ACS APPLIED ENERGY MATERIALS (2020)

Article Electrochemistry

Effects of Film Formation on the Electrodeposition of Lithium

Kazuki Yoshii, Hisao Kiuchi, Noboru Taguchi, Masahiro Shikano, Eiichiro Matsubara, Hikari Sakaebe

CHEMELECTROCHEM (2020)

Article Chemistry, Physical

All-Solid-State Batteries with LiCoO2-Type Electrodes: Realization of an Impurity-Free Interface by Utilizing a Cosinterable Li3.5Ge0.5V0.5O4 Electrolyte

Toyoki Okumura, Tomonari Takeuchi, Hironori Kobayashi

Summary: An impurity-free interface was achieved in an oxide-based all-solid-state battery (ASSB) through cosintering, with enhanced thermal stability between the LiMO electrode materials and LISICON-type LGVO electrolyte. The high ionic conductivity of LGVO facilitated good reversible capacity in the NMC electrode, making it a promising property in oxide-based ASSBs.

ACS APPLIED ENERGY MATERIALS (2021)

Article Multidisciplinary Sciences

Mixed alkali-ion transport and storage in atomic-disordered honeycomb layered NaKNi2TeO6

Titus Masese, Yoshinobu Miyazaki, Josef Rizell, Godwill Mbiti Kanyolo, Chih-Yao Chen, Hiroki Ubukata, Keigo Kubota, Kartik Sau, Tamio Ikeshoji, Zhen-Dong Huang, Kazuki Yoshii, Teruo Takahashi, Miyu Ito, Hiroshi Senoh, Jinkwang Hwang, Abbas Alshehabi, Kazuhiko Matsumoto, Toshiyuki Matsunaga, Kotaro Fujii, Masatomo Yashima, Masahiro Shikano, Cedric Tassel, Hiroshi Kageyama, Yoshiharu Uchimoto, Rika Hagiwara, Tomohiro Saito

Summary: Honeycomb layered oxides are a class of emerging materials with peculiar physicochemical properties. The authors report the synthesis and electrochemical energy storage characterizations of a mixed-alkali honeycomb layered oxide material capable of storing Na and K ions simultaneously.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Extending the Frontiers of Lithium-Ion Conducting Oxides: Development of Multicomponent Materials with ?-Li3PO4-Type Structures

Guowei Zhao, Kota Suzuki, Toyoki Okumura, Tomonari Takeuchi, Masaaki Hirayama, Ryoji Kanno

Summary: In this study, lithium superionic conductors with gamma-Li3PO4-type structures were developed to investigate the multicomponent effects on ion-conducting properties. The results showed that framework cations with larger ionic radii exhibited enhanced conductive properties, and the changes in ionic conductivity associated with the ionic radius were larger in ternary systems than those in binary systems.

CHEMISTRY OF MATERIALS (2022)

Article Nanoscience & Nanotechnology

Fabrication of Oxide-Based All-Solid-State Batteries by a Sintering Process Based on Function Sharing of Solid Electrolytes

Miyuki Sakakura, Kazutaka Mitsuishi, Toyoki Okumura, Norikazu Ishigaki, Yasutoshi Iriyama

Summary: Combining Garnet-type LLZ and LISICON-type LGVO as a multilayer solid electrolyte sheet can effectively reduce reactivity issues during the sintering process, improving the performance and cycle life of solid-state batteries.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Chemistry, Physical

5D Analysis of Capacity Degradation in Battery Electrodes Enabled by Operando CT-XANES

Yuta Kimura, Su Huang, Takashi Nakamura, Nozomu Ishiguro, Oki Sekizawa, Kiyofumi Nitta, Tomoya Uruga, Tomonari Takeuchi, Toyoki Okumura, Mizuki Tada, Yoshiharu Uchimoto, Koji Amezawa

Summary: A method combining operando computed tomography and X-ray absorption near-edge structure spectroscopy (CT-XANES) is proposed in this paper to directly track the evolution of the 3D distribution of local capacity loss in battery electrodes. The method enables a five-dimensional analysis of degradation, including spatial coordinates, time, and chemical state. It quantifies the spatiotemporal dynamics of local capacity degradation and correlates it with overall electrode performance, providing critical insights for identifying degradation factors and developing batteries with long-term stability.

SMALL METHODS (2023)

Article Chemistry, Multidisciplinary

Zr- and Ce-doped Li6Y(BO3)3 electrolyte for all-solid-state lithium-ion battery

Toyoki Okumura, Yoshitaka Shiba, Noriko Sakamoto, Takeshi Kobayashi, Saori Hashimoto, Kentaro Doguchi, Harunobu Ogaki, Tomonari Takeuchi, Hironori Kobayashi

Summary: By substituting tetravalent ions and creating vacancies, the ionic conductivity of Li6Y(BO3)(3) (LYBO) was enhanced, leading to good reversible capacities in solid-state batteries.

RSC ADVANCES (2021)

Article Nanoscience & Nanotechnology

Effect of vanadium substitution in LixFeF3 by first-principles calculations

Masahiro Mori, Shingo Tanaka, Masahiro Shikano, Hikari Sakaebe

Summary: By calculating the stable atomic and electronic states of vanadium-substituted trirutile-type LixFeF3, it was found that the x = 0.50 configurations were the most stable for all y values studied. In cases where Fe and V coexisted, compositions with the same Li insertion as Fe substitution were energetically stable. The results suggest that Fe (or V) in LixFe1-yVyF3 preferentially decreases (or increases) its formal valence state with Li insertion.

AIP ADVANCES (2021)

Article Chemistry, Physical

Capacity fading mechanism of conversion-type FeF3 electrode: Investigation by electrochemical operando nuclear magnetic resonance spectroscopy

Keiji Shimoda, Masahiro Shikano, Miwa Murakami, Hikari Sakaebe

JOURNAL OF POWER SOURCES (2020)

Article Chemistry, Multidisciplinary

New insight derived from a two-compartment cell: electrochemical behavior of FeF3 positive electrode

Kazuki Yoshii, Noboru Taguchi, Takeshi Miyazaki, Masahiro Shikano, Hikari Sakaebe

CHEMICAL COMMUNICATIONS (2020)

Article Chemistry, Physical

LISICON-Based Amorphous Oxide for Bulk-Type All-Solid-State Lithium-Ion Battery

Toyoki Okumura, Sou Taminato, Yoshinobu Miyazaki, Michinori Kitamura, Tomohiro Saito, Tomonari Takeuchi, Hironori Kobayashi

ACS APPLIED ENERGY MATERIALS (2020)

Article Chemistry, Physical

Development of a tubular direct carbon solid oxide fuel cell stack based on lanthanum gallate electrolyte

Tianyu Chen, Zhibin Lu, Guangjin Zeng, Yongmin Xie, Jie Xiao, Zhifeng Xu

Summary: The study introduces a high-performance LSGM electrolyte-supported tubular DC-SOFC stack for portable applications, which shows great potential in developing into high-performing, efficient, and environmentally friendly portable power sources for distributed applications.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Construction of ultrastable and high-rate performance zinc anode with three-dimensional porous structure and Schottky contact

Wenbin Tong, Yili Chen, Shijie Gong, Shaokun Zhu, Jie Tian, Jiaqian Qin, Wenyong Chen, Shuanghong Chen

Summary: In this study, a three-dimensional porous NiO interface layer with enhanced anode dynamics is fabricated, forming a Schottky contact with the zinc substrate, allowing rapid and uniform zinc plating both inside and below the interface layer. The resulting NiO@Zn exhibits exceptional stability and high capacity retention.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Flexible low-temperature zinc ion supercapacitor based on gel electrolyte with α-MnO2@rGO electrode

Yafeng Bai, Kaidi Li, Liying Wang, Yang Gao, Xuesong Li, Xijia Yang, Wei Lu

Summary: In this study, a flexible zinc ion supercapacitor with gel electrolytes, porous alpha-MnO2@reduced graphene oxide cathode, and activated carbon/carbon cloth anode was developed. The device exhibits excellent electrochemical performance and stability, even at low temperatures, with a high cycle retention rate after 5000 cycles.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Examining the effects of silicon based additives on the long-term cycling capabilities of cylindrical cells

Anmol Jnawali, Matt D. R. Kok, Francesco Iacoviello, Daniel J. L. Brett, Paul R. Shearing

Summary: This article presents the results of a systematic study on the electrochemical performance and mechanical changes in two types of commercial batteries with different anode chemistry. The study reveals that the swelling of anode layers in batteries with silicon-based components causes deformations in the jelly roll structure, but the presence of a small percentage of silicon does not significantly impact the cycling performance of the cells within the relevant state-of-health range for electric vehicles (EVs). The research suggests that there is room for improving the cell capacities by increasing the silicon loading in composite anodes to meet the increasing demands on EVs.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Lithium disilicate as an alternative silicate battery material. A theoretical study

Yohandys A. Zulueta, My Phuong Pham-Ho, Minh Tho Nguyen

Summary: Advanced atomistic simulations were used to study ion transport in the Na- and K-doped lithium disilicate Li2Si2O5. The results showed that Na and K doping significantly enhanced Li ion diffusion and conduction in the material.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Novel BaO-decorated carbon-tolerant Ni-YSZ anode fabricated by an efficient phase inversion-impregnation approach

Zongying Han, Hui Dong, Yanru Yang, Hao Yu, Zhibin Yang

Summary: An efficient phase inversion-impregnation approach is developed to fabricate BaO-decorated Ni8 mol% YSZ anode-supported tubular solid oxide fuel cells (SOFCs) with anti-coking properties. BaO nanoislands are successfully introduced inside the Ni-YSZ anode, leading to higher peak power densities and improved stability in methane fuel. Density functional theory calculations suggest that the loading of BaO nanoislands facilitates carbon elimination by capturing and dissociating H2O molecules to generate OH.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Safe and stable Li-CO2 battery with metal-organic framework derived cathode composite and solid electrolyte

Suresh Mamidi, Dan Na, Baeksang Yoon, Henu Sharma, Anil D. Pathak, Kisor Kumar Sahu, Dae Young Lee, Cheul-Ro Lee, Inseok Seo

Summary: Li-CO2 batteries, which utilize CO2 and have a high energy density, are hindered in practical applications due to slow kinetics and safety hazards. This study introduces a stable and highly conductive ceramic-based solid electrolyte and a metal-organic framework catalyst to improve the safety and performance of Li-CO2 batteries. The optimized Li-CO2 cell shows outstanding specific capacity and cycle life, and the post-cycling analysis reveals the degradation mechanism of the electrodes. First-principles calculations based on density functional theory are also performed to understand the interactions between the catalyst and the host electrode. This research demonstrates the potential of MOF cathode catalyst for stable operation in Li-CO2 batteries.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Synergistic effect of platinum single atoms and nanoclusters for preferential oxidation of carbon monoxide in hydrogen-rich stream

Ganghua Xiang, Zhihuan Qiu, Huilong Fei, Zhigang Liu, Shuangfeng Yin, Yuen Wu

Summary: In this study, a CeFeOx-supported Pt single atoms and subnanometric clusters catalyst was developed, which exhibits enhanced catalytic activity and stability for the preferential oxidation of CO in H2-rich stream through synergistic effect.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Towards understanding the functional mechanism and synergistic effects of LiMn2O4-LiNi0.5Mn0.3Co0.2O2 blended positive electrodes for Lithium-ion batteries

Dimitrios Chatzogiannakis, Marcus Fehse, Maria Angeles Cabanero, Natalia Romano, Ashley Black, Damien Saurel, M. Rosa Palacin, Montse Casas-Cabanas

Summary: By coupling electrochemical testing to operando synchrotron based X-ray absorption and powder diffraction experiments, blended positive electrodes consisting of LiMn2O4 spinel (LMO) and layered LiNi0.5Mn0.3Co0.2O2 (NMC) were studied to understand their redox mechanism. It was found that blending NMC with LMO can enhance energy density at high rates, with the blend containing 25% LMO showing the best performance. Testing with a special electrochemical setup revealed that the effective current load on each blend component can vary significantly from the nominal rate and also changes with SoC. Operando studies allowed monitoring of the oxidation state evolution and changes in crystal structure, in line with the expected behavior of individual components considering their electrochemical current loads.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

We may be underestimating the power capabilities of lithium-ion capacitors

Chiara Cementon, Daniel Dewar, Thrinathreddy Ramireddy, Michael Brennan, Alexey M. Glushenkov

Summary: This Perspective discusses the specific power and power density of lithium-ion capacitors, highlighting the fact that their power characteristics are often underestimated. Through analysis, it is found that lithium-ion capacitors can usually achieve power densities superior to electrochemical supercapacitors, making them excellent alternatives to supercapacitors.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Highly concentrated solvation structure for reversible high-voltage lithium-ion battery at low temperature

Weihao Wang, Hao Yu, Li Ma, Youquan Zhang, Yuejiao Chen, Libao Chen, Guichao Kuang, Liangjun Zhou, Weifeng Wei

Summary: This study achieved an improved electrolyte with excellent low-temperature and high-voltage performance by regulating the Li+ solvation structure and highly concentrating it. The electrolyte exhibited outstanding oxidation potential and high ionic conductivity under low temperature and high voltage conditions, providing a promising approach for the practical application of high-voltage LIBs.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Evaluation of mitigation of capacity decay in vanadium redox flow batteries for cation- and anion-exchange membrane by validated mathematical modelling

Martin Bures, Dan Gotz, Jiri Charvat, Milos Svoboda, Jaromir Pocedic, Juraj Kosek, Alexandr Zubov, Petr Mazur

Summary: Vanadium redox flow battery is a promising energy storage solution with long-term durability, non-flammability, and high overall efficiency. Researchers have developed a mathematical model to simulate the charge-discharge cycling of the battery, and found that hydraulic connection of electrolyte tanks is the most effective strategy to reduce capacity losses, achieving a 69% reduction.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Operando analysis of the positive active mass of lead batteries by neutron diffraction

M. Rodriguez-Gomez, J. Campo, A. Orera, F. de La Fuente, J. Valenciano, H. Fricke, D. S. Hussey, Y. Chen, D. Yu, K. An, A. Larrea

Summary: In this study, we analysed the operando performance of industrial lead cells using neutron diffraction experiments. The experiments revealed the evolution of different phases in the positive electrode, showed significant inhomogeneity of phase distribution inside the electrode, and estimated the energy efficiency of the cells.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Double Conductive Ni-pads for a kW-class micro-tubular solid oxide fuel cell stack

Jiawei Liu, Chenpeng Wang, Yue Yao, Hao Ye, Yinglong Liu, Yingli Liu, Xiaoru Xu, Zhicong Chen, Huazheng Yang, Gang Wu, Libin Lei, Chao Wang, Bo Liang

Summary: The study focuses on utilizing double conductive Ni-pads as anode collectors in micro-tubular solid oxide fuel cells. The simulation results show excellent performance and stability of DCNPs, and also highlight the potential applications in various fields.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Ion transport regulation of polyimide separator for safe and durable Li-metal battery

Yang Wang, Kangjie Zhou, Lang Cui, Jiabing Mei, Shengnan Li, Le Li, Wei Fan, Longsheng Zhang, Tianxi Liu

Summary: This study presents a polyimide sandwiched separator (s-PIF) for improving the cycling stability of Li-metal batteries. The s-PIF separator exhibits superior mechanical property, electrolyte adsorption/retention and ion conductivity, and enables dendrite-free Li plating/stripping process.

JOURNAL OF POWER SOURCES (2024)