Journal
JOURNAL OF POROUS MATERIALS
Volume 22, Issue 1, Pages 211-218Publisher
SPRINGER
DOI: 10.1007/s10934-014-9887-3
Keywords
Nanoscale cavity; Mesoporous silica; Recyclable nanoreactor; Nitriles
Funding
- Razi University Research Council
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A novel method for the synthesis of SBA-15-Pr-NMe3OH as a nanoreactor heterogenous Bronsted base catalyst has been developed. Quaternary organic tetraalkylammonium hydroxide grafted on SBA-15 is a strong Bronsted base catalyst, and represents a useful alternative to soluble bases in the selective conversion of nitriles to amides with aqueous 30 % H2O2, presenting high efficiency, convenient recovery and steady reuse.
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