4.5 Article

Development of novel porous carbon frameworks through hydrogen-bonding interaction and its ethylene adsorption activity

Journal

JOURNAL OF POROUS MATERIALS
Volume 19, Issue 4, Pages 519-527

Publisher

SPRINGER
DOI: 10.1007/s10934-012-9565-2

Keywords

Adsorption; Composite; Evaporation induced self assembly method (EISA); Polymerization; Porous carbon materials; Porous media

Funding

  1. Dongguk University, Republic of Korea

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Porous carbon materials are widely used in separation, catalysis and energy storage/conversion. We have synthesized a new porous carbon material by solvent evaporation induced self assembly method using hydroquinone/formaldehyde as a precursor which can help self assembly with template triblock copolymer PEO-PPO-PEO (F127). The template removal have resulted the porous carbon material (PCM) framework upon carbonization. We have also prepared porous carbon fibers (PCF) using kapok fibers along with hydroquinone/formaldehyde/F127 and observed its ethylene adsorption capacity. Kapok fibers were obtained from the plant species Ceiba pentandra. The characterization of PCM and PCF were accomplished by microanalysis, powder X-ray diffraction, FTIR, scanning electron microscopy, transmission electron microscopy, thermo-gravimetric analysis, elemental analysis and N-2 adsorption-desorption isotherm. The prepared carbon materials (PCM and PCF) showed excellent gas absorption ability towards ethylene gas at room temperature as well as at 50 A degrees C.

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