4.5 Article

Improvements of the dielectric constant and ferromagnetic property of Co doped BiFeO3 nanotubes

Journal

JOURNAL OF POROUS MATERIALS
Volume 20, Issue 4, Pages 727-731

Publisher

SPRINGER
DOI: 10.1007/s10934-012-9647-1

Keywords

BiFeO3; Co2+ doping; Nanotube arrays; Dielectric; Ferromagnetic

Funding

  1. Natural Science Foundation of China [11074193, 51132001, 50902108]

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Ordered BiFeO3 (BFO) and BiFe0.95Co0.05O3 (BFC) nanotubes arrays were successfully synthesized by a sol-gel anodic aluminum oxide template method. Both kinds of nanotubes had straight and smooth profiles with diameters of about 200 nm and wall thicknesses of about 20 nm. A perovskite-type structure of BFO was confirmed in these nanotubes by high-resolution transmission electron microscopy. The dielectric properties of these nanotube arrays were measured and larger permittivity was obtained for the BFC nanotubes via adopting a columnar composite structure model. Ferromagnetic measurement showed enhanced ferromagnetism for the sample with Co2+ doping. These improvements in dielectric constant and ferromagnetism of the nanotubes by Co2+ doping may be mainly attributed, respectively, to the lattice distortion and the breakage of the spin cycloid period of the BFC nanotubes.

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