4.2 Article

Synthesis of POSS-Polyurethane Hybrids Using Octakis(m-isoprenyl-α,α′-dimethylbenzylisocyanato dimethylsiloxy) octasilsesquioxane (Q8M8TMI) as a Crosslinking Agent

Journal

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 51, Issue 23, Pages 5038-5045

Publisher

WILEY-BLACKWELL
DOI: 10.1002/pola.26934

Keywords

differential scanning calorimetry; polyurethanes; thermogravimetric analysis

Ask authors/readers for more resources

A series of polyurethane hybrid networks have been synthesized using octakis(m-isoprenyl-,-dimethylbenzylisocyanato dimethylsiloxy) octasilsesquioxane (Q(8)M(8)(TMI)) as a crosslinking agent. The formation of the urethane linkages within the polyurethane hybrids was confirmed by photoacoustic FTIR spectroscopy. The TGA and DSC studies demonstrated that the incorporation of the POSS crosslinking agents altered the thermal properties of the polyurethanes, and that this was dependent on the length of the polyethylene glycol chain. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 5038-5045

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.2
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

Polycrystalline Advanced Microporous Framework Membranes for Efficient Separation of Small Molecules and Ions

Jue Hou, Huacheng Zhang, George P. Simon, Huanting Wang

ADVANCED MATERIALS (2020)

Article Chemistry, Physical

Intrinsically Stretchable Fuel Cell Based on Enokitake-Like Standing Gold Nanowires

Qingfeng Zhai, Yiyi Liu, Ren Wang, Yan Wang, Quanxia Lyu, Shu Gong, Joseph Wang, George P. Simon, Wenlong Cheng

ADVANCED ENERGY MATERIALS (2020)

Article Chemistry, Analytical

Vertically Aligned Gold Nanowires as Stretchable and Wearable Epidermal Ion-Selective Electrode for Noninvasive Multiplexed Sweat Analysis

Qingfeng Zhai, Lim Wei Yap, Ren Wang, Shu Gong, Zhirui Guo, Yiyi Liu, Quanxia Lyu, Joseph Wang, George P. Simon, Wenlong Cheng

ANALYTICAL CHEMISTRY (2020)

Article Polymer Science

Design and fabrication of transdermal drug delivery patch with milliprojections using material extrusion 3D printing

Tiffany Obog Tang, Susan Holmes, Katherine Dean, George Philip Simon

JOURNAL OF APPLIED POLYMER SCIENCE (2020)

Article Polymer Science

Biodegradation of 3D-printed polylactic acid milliprojections under physiological conditions

Tiffany Obog Tang, George Philip Simon

JOURNAL OF APPLIED POLYMER SCIENCE (2020)

Article Chemistry, Analytical

Development of a Paper-Based Microfluidic System for a Continuous High-Flow-Rate Fluid Manipulation

Mahdi Naseri, George P. Simon, Warren Batchelor

ANALYTICAL CHEMISTRY (2020)

Article Engineering, Chemical

Microporous polymer incorporated polyamide membrane for reverse osmosis desalination

Shasha Feng, Ze-Xian Low, Shasha Liu, Lian Zhang, Xiwang Zhang, George P. Simon, Xi-Ya Fang, Huanting Wang

JOURNAL OF MEMBRANE SCIENCE (2020)

Article Chemistry, Multidisciplinary

Selective Permeation of Water through Angstrom-Channel Graphene Membranes for Bioethanol Concentration

Xiaofang Chen, Shabin Mohammed, Guang Yang, Tianyue Qian, Yu Chen, Hongyu Ma, Zongli Xie, Xiwang Zhang, George P. Simon, Huanting Wang

ADVANCED MATERIALS (2020)

Article Nanoscience & Nanotechnology

Electrolyte gating in graphene-based supercapacitors and its use for probing nanoconfined charging dynamics

Jing Xiao, Hualin Zhan, Xiao Wang, Zai-Quan Xu, Zhiyuan Xiong, Ke Zhang, George P. Simon, Jefferson Zhe Liu, Dan Li

NATURE NANOTECHNOLOGY (2020)

Article Green & Sustainable Science & Technology

A sunlight-responsive metal-organic framework system for sustainable water desalination

Ranwen Ou, Huacheng Zhang, Vinh X. Truong, Lian Zhang, Hanaa M. Hegab, Li Han, Jue Hou, Xiwang Zhang, Ana Deletic, Lei Jiang, George P. Simon, Huanting Wang

NATURE SUSTAINABILITY (2020)

Article Chemistry, Applied

Controlling the transparency and rheology of nanocellulose gels with the extent of carboxylation

David Joram Mendoza, Laila Hossain, Christine Browne, Vikram Singh Raghuwanshi, George P. Simon, Gil Garnier

CARBOHYDRATE POLYMERS (2020)

Article Chemistry, Multidisciplinary

Grafting Nature-Inspired and Bio-Based Phenolic Esters onto Cellulose Nanocrystals Gives Biomaterials with Photostable Anti-UV Properties

David Joram Mendoza, Louis M. M. Mouterde, Christine Browne, Vikram Singh Raghuwanshi, George P. Simon, Gil Garnier, Florent Allais

CHEMSUSCHEM (2020)

Article Chemistry, Physical

Modulating transparency and colour of cellulose nanocrystal composite films by varying polymer molecular weight

Maoqi Lin, Vikram Singh Raghuwanshi, Christine Browne, George P. Simon, Gil Garnier

Summary: The study found that by adjusting the molecular weight and concentration of the polymer, the optical properties of the composite film can be changed to reflect light at different wavelengths. The cholesteric structure and molecular weight have a significant impact on the optical properties of the film.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Article Engineering, Chemical

Cyclodextrin metal-organic framework-polymer composite membranes towards ultimate and stable enantioselectivity

Yizhihao Lu, Jun Yong Chan, Huacheng Zhang, Xingya Li, Yada Nolvachai, Philip J. Marriott, Xiwang Zhang, George P. Simon, Mark M. Banaszak Holl, Huanting Wang

Summary: This study demonstrates ultrahigh and stable enantioselectivity using CD-MOF/PES mixed-matrix membranes. The decline of membrane enantioselectivity is found to be influenced by the interaction of solvent with chiral molecules and MOF structure. This work provides a new strategy for designing enantioselective membranes based on homochiral MOFs.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Chemistry, Physical

A thermally reduced graphene oxide membrane interlayered with an in situ synthesized nanospacer for water desalination

Hongyu Ma, Xiaofang Chen, Shabin Mohammed, Yaoxin Hu, Jun Lu, George P. Simon, Hongjuan Hou, Huanting Wang

JOURNAL OF MATERIALS CHEMISTRY A (2020)

No Data Available