Article
Polymer Science
Kumar Divya, Meenakshi Sundaram Sri Abirami Saraswathi, Alagumalai Nagendran, Dipak Rana
Summary: In this study, hybrid membranes based on sulfonated chitosan and copper-based metal-organic frameworks were fabricated and investigated for direct methanol fuel cell applications. The results showed that the incorporation of copper-based metal-organic frameworks improved the membrane performances, resulting in lower methanol permeability and higher proton conductivity.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Polymer Science
Roberto Teruel-Juanes, Carmen del Rio, Oscar Gil-Castell, Carmem Primaz, Amparo Ribes-Greus
Summary: SEBS membranes with DVB as a crosslinking agent and post-sulfonation were evaluated for fuel cell applications. The study showed that membranes with mild post-sulfonation exhibited higher proton conductivity compared to those with excessive sulfonation, leading to promising power density in fuel cell performance. Despite challenges in charge transport, the membranes showed potential for use as cost-effective polyelectrolytes in fuel cells.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Polymer Science
Cataldo Simari, Isabella Nicotera, Antonino Salvatore Arico, Vincenzo Baglio, Francesco Lufrano
Summary: This study investigates the methanol transport properties of composite membranes to reduce methanol crossover in DMFCs, improving the performance and making it a viable option for high-energy DMFCs.
Article
Engineering, Chemical
Dongxia Liang, Chenglong Wu, Lu Liu, Hansheng Li, Qin Wu, Daxin Shi, Yaoyuan Zhang, Kangcheng Chen
Summary: Coupling-type sulfonated poly(phenylquinoxaline) (c-SPPQ) with side chain and main chain sulfonic acid groups was synthesized through post-sulfonation. Proton exchange membranes made from c-SPPQ exhibited good performance, including low methanol permeability, high methanol tolerance, and good mechanical properties due to acid-base interaction of sulfonic acid and phenylquinoxaline groups. The superior conductivity and low methanol permeability of c-SPPQ make it a promising material for direct methanol fuel cells.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Biochemistry & Molecular Biology
Livhuwani Modau, Rudzani Sigwadi, Touhami Mokrani, Fulufhelo Nemavhola
Summary: The purpose of this study was to identify the steps involved in fabricating silica/chitosan composite membranes and their suitability for fuel cell applications. The composite membranes were successfully modified with silica, showing exceptional results in terms of proton conductivity and methanol permeability.
Article
Chemistry, Applied
Bin Wang, Xing Han, Yi Wang, Lu Kang, Yudong Yang, Liying Cui, Shuangling Zhong, Xuejun Cui
Summary: Alginate-based multi-crosslinked biomembranes (ABMCBs) were prepared with sodium alginate as matrix and functionalized organosilane as additive. ABMCB-4 with 40 wt% additive exhibited optimal selectivity and maximum power density, showing potential adaptability for direct methanol fuel cell application.
CARBOHYDRATE POLYMERS
(2023)
Article
Polymer Science
Kosar Arab, Mahdi Tohidian, Amirsaeed Shamsabadi
Summary: In this study, nanocomposite polyelectrolyte membranes based on sulfonated polystyrene (SPS) and imidazole-2-acetic acid (Im) blend (SPSIm), incorporated with halloysite nanotubes (HNTs), were investigated for direct methanol fuel cell (DMFC) applications. The optimal degree of sulfonation for PS was selected based on hydrolytic stability, and SPS was blended with Im to improve proton conductivity and decrease methanol permeability. The addition of HNTs further reduced methanol crossover by introducing tortuous diffusion pathways. The resulting SPSIm/HNT membrane showed significantly decreased methanol permeability and improved membrane selectivity parameter, making it a potential candidate for DMFC applications.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Polymer Science
Gilberto Ramos-Rivera, David Suleiman
Summary: Two series of poly(arylene ether sulfone)s with hydrophobic blocks were synthesized and blended with SIBS to obtain strong and flexible membranes. The resulting membranes exhibited low water absorption and high thermal stability, making them suitable for direct methanol fuel cell applications. Incorporating SIBS enhanced transport properties and proton conductivities, surpassing Nafion (R) 117 in selectivity.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Biochemistry & Molecular Biology
Dongxia Liang, Qin Wu, Daxin Shi, Yaoyuan Zhang, Hansheng Li, Kangcheng Chen
Summary: In this study, side-chain type sulfonated poly(phenylquinoxaline) proton exchange membranes with different ionic exchange capacity were synthesized and demonstrated to have higher proton conductivity and stability.
Article
Engineering, Environmental
Guoliang Liu, Ailian Wang, Wenxi Ji, Fangfang Zhang, Jianing Wu, Taoyi Zhang, Haolin Tang, Haining Zhang
Summary: The in situ crosslinking side reaction is ingeniously controlled during the preparation of quaternized polybenzimidazole (PBI) based anion exchange membranes (AEMs) to achieve a balance between mechanical properties and ionic conductivity. The results show that the in situ crosslinking reaction is easy to occur and has better crosslinking effect than traditional strategies. Additionally, the in situ crosslinking greatly improves the mechanical properties of quaternized PBI membranes and ensures reasonable hydroxide conduction. Rating: 7 points.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Biochemistry & Molecular Biology
Jamaliah Aburabie, Boor Lalia, Raed Hashaikeh
Summary: This work presents the development of sulfated cellulose (SC) polymer and its potential as an electrolyte-membrane for direct methanol fuel cells (DMFC). The ion-conductive crosslinked SC membranes showed high methanol resistivity and proton conductivity, addressing a major hurdle in the widespread application of direct alcohol fuel cells. Compared to Nafion membranes, the crosslinked sulfated cellulose films have lower ion conductivity but significantly lower methanol crossover.
Article
Energy & Fuels
Lukka Thuyavan Yogarathinam, Juhana Jaafar, Ahmad Fauzi Ismail, Hazlina Junoh, Alireza Samavati, Pei Sean Goh, Arthanareeswaran Gangasalam, Jerome Peter
Summary: This study incorporated conductive polyaniline deposited oxidized graphitic carbon nitride into sulfonated poly (ether ether ketone) membrane for direct methanol fuel cell applications. The functionalized membrane showed improved water uptake capacity, ion exchange capacity, lower methanol permeability, higher proton conductivity, and higher oxidative stability. These results demonstrate the potential of the modified membrane as a superior nanofiller for PEM modification in DMFC applications.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Chemistry, Applied
Ying Ou, Ting Qu, Fan Cheng, Haiyang Yang, Fuqiang Hu, Jie Wang, Hai Liu, Guoliang Liu, Sheng Wen, Chunli Gong
Summary: In this study, the mechanical stability and ionic conductivity of highly quaternized chitosan (HQCS) were improved by in-situ ionic crosslinking, and a mechanically robust hydroxide ion conduction network was introduced using quaternized electrospun poly(vinylidene fluoride) (QPVDF) nanofiber. The resulting composite membrane exhibited excellent dimensional stability, mechanical performance, alkaline stability, and ionic conductivity, making it suitable for alkaline direct methanol fuel cells with satisfactory durability.
CARBOHYDRATE POLYMERS
(2023)
Article
Chemistry, Physical
Weidong Cui, Shengyang Zhou, Jie Bai, Huidong Qian, Jifu Zheng, Shenghai Li, Suobo Zhang
Summary: The development of a simple and efficient methanol-resistant membrane strategy is crucial for enhancing fuel cell performance. By blending SCTF nanosheets with SPP-co-PAEKs resin, a composite proton exchange membrane with improved proton conductivity, methanol resistance, and fuel cell performance was successfully prepared. This enhancement is attributed to the good interfacial compatibility between the SCTF nanosheets and the sulfonated micro-block copolymer matrix.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Polymer Science
Hang Fan, Tiantian Xie, Yang Pang, Shiyang Zhu, Pengju Feng, Xuanbo Zhu, Chengji Zhao, Shaowei Guan, Hongyan Yao
Summary: A collaborative strategy of main-chain and molecular-network engineering was applied to develop cross-linked sulfonated polyimide membranes (CSPI) with excellent methanol resistance and dimensional stability. The CSPI membranes exhibited high proton conductivity, low swelling ratio, and methanol permeability, making them promising candidates for direct methanol fuel cell applications.
MACROMOLECULAR RAPID COMMUNICATIONS
(2023)