Journal
JOURNAL OF PHYSICS-CONDENSED MATTER
Volume 21, Issue 25, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/0953-8984/21/25/255401
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Funding
- GA AV project [IAA100100514]
- AV CR [AV0Z-10100521]
- European Synchrotron Radiation Facility (ESRF) [HS-3074]
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Cu K-edge x-ray absorption near-edge structure (XANES) spectra of trigonal (3R) CuScO(2) and CuLaO(2) and of hexagonal (2H) CuScO(2) were investigated experimentally and theoretically, in order to study differences between spectra of isostructural and isoelectronic compounds. Significant differences were found in the Cu K-edge XANES of 3R CuScO(2) and 3R CuLaO(2); these differences can be understood by considering the calculated polarization dependence of the XANES spectra and the differences between the phaseshifts of Sc and La. Spectra of the 3R and 2H polytypes of CuScO(2) differ only weakly and the difference originates from the long-range order. The pre-edge peak around 8980 eV is generated by the same mechanism as the pre-edge peak in Cu(2)O, i.e. involving scattering by the Cu atoms in the plane which is perpendicular to the O-Cu-O axis.
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