4.6 Article

Process dependence of H passivation and doping in H-implanted ZnO

Journal

JOURNAL OF PHYSICS D-APPLIED PHYSICS
Volume 46, Issue 5, Pages -

Publisher

IOP PUBLISHING LTD
DOI: 10.1088/0022-3727/46/5/055107

Keywords

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Funding

  1. National Science Foundation [DMR-0803276]
  2. Norwegian Research Centre for Solar Cell Technology, a Centre for Environment-friendly Energy Research [193829]
  3. Norwegian Research Council
  4. AFOSR [FA9550-10-1-0079]
  5. AFRL [HC1047-05-D-4005]
  6. Norwegian Research Council through the NANOMAT
  7. Norwegian Research Council through FRINATEK program
  8. Direct For Mathematical & Physical Scien
  9. Division Of Materials Research [0803276] Funding Source: National Science Foundation
  10. Directorate For Engineering
  11. Div Of Electrical, Commun & Cyber Sys [823805] Funding Source: National Science Foundation

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We used depth-resolved cathodoluminescence spectroscopy (DRCLS), photoluminescence (PL) spectroscopy and temperature-dependent Hall-effect (TDHE) measurements to describe the strong dependence of H passivation and doping in H-implanted ZnO on thermal treatment. Increasing H implantation dose increases passivation of Zn and oxygen vacancy-related defects, while reducing deep level emissions. Over annealing temperatures of 100-400 degrees C at different times, 1 h annealing at 200 degrees C yielded the lowest DRCLS deep level emissions, highest TDHE carrier mobility, and highest near band-edge PL emission. These results describe the systematics of dopant implantation and thermal activation on H incorporation in ZnO and their effects on its electrical properties.

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