Article
Spectroscopy
Jaime Orejas, Yinchenxi Zhang, Cristian Soto-Gancedo, Luis Javier Fernandez-Menendez, Jorge Pisonero, Nerea Bordel
Summary: The Solution-Cathode Glow Discharge (SCGD) is a plasma source that provides simplicity and low consumption for elemental analysis. When combined with Optical Emission Spectrometry (OES), it can achieve ng/mL limits of detection for multiple elements. This study focuses on fundamental plasma diagnostics of SCGD and investigates how dissolved ions in the sample solution affect the performance of the analysis.
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
(2023)
Article
Optics
Hans Hoeft, Markus M. Becker, Manfred Kettlitz, Simon Dap, Nicolas Naude, Ronny Brandenburg, Klaus-Dieter Weltmann
Summary: The effects of nitrous oxide (N2O) in nitrogen (N-2) on the development and morphology of sine driven dielectric barrier discharges were studied. The characteristics of the discharge and its development were analyzed through various measurements and numerical modeling. The results showed that even with small amounts of N2O, the associative ionization of atomic nitrogen and oxygen played a crucial role in sustaining the volume memory effect and causing the formation of a diffuse discharge.
EUROPEAN PHYSICAL JOURNAL D
(2023)
Article
Physics, Fluids & Plasmas
Naoki Shirai, Hiroki Owada, Koichi Sasaki
Summary: An efficient method for generating OH radicals in the spatial afterglow of atmospheric-pressure plasma was investigated, which utilized intersecting helium flows and a DC glow discharge, with water vapor admixed at the intersection point for OH radicals formation and transportation to the afterglow zone.
PLASMA SOURCES SCIENCE & TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Qianhan Han, Ying Guo, Yarong Zhang, Jing Zhang, Jianjun Shi
Summary: In this experimental study, a plasma plume generated by radio frequency atmospheric pressure glow discharge was enhanced in terms of length and intensity by pulsed discharge. The enhanced plume was used to improve the O/C ratio of carbon fiber.
APPLIED SCIENCES-BASEL
(2022)
Article
Chemistry, Analytical
Krzysztof Greda, Maja Welna, Anna Szymczycha-Madeja, Pawel Pohl
Summary: For the first time, a dispersive micro-solid phase extraction (D-mu SPE) based on graphene oxide was used for the ultrasensitive determination of Cd. With this method, Cd can be efficiently extracted from a mixture of alkali and alkaline earth metals without the need for an elution step. The combination of D-mu SPE and SAGD OES significantly reduces matrix effects and improves the tolerance of Cd to alkali metals. The method shows simplicity in the measurement system and the commercially available nanosorbent used.
MICROCHEMICAL JOURNAL
(2024)
Review
Spectroscopy
Brian T. Molnar, Jacob T. Shelley
Summary: Plasmas have been used as ionization sources in mass spectrometry experiments since the early days of Thomson and Aston. Plasma ion sources were chosen because they were one of the few known sources of gas-phase ions at the time and were relatively easy to set up and operate. The development of plasma ionization has led to advancements in mass spectrometry and laid the foundation for ionization approaches, mass analysis, and detection methods for very large molecules.
MASS SPECTROMETRY REVIEWS
(2021)
Article
Chemistry, Analytical
Ling Qian, Zhendong Lei, Xiaoxu Peng, Guangzhi Yang, Zheng Wang
Summary: In this study, a fast and simple method for highly sensitive detection of Cd and Pb elements based on APGD-AES coupling with tungsten coil ETV was proposed. The system showed good accuracy in determining heavy metals in standard samples and human whole blood, with results comparable to ICP-MS.
ANALYTICA CHIMICA ACTA
(2021)
Article
Chemistry, Analytical
Monika Gorska, Pawel Pohl, Krzysztof Greda
Summary: Investigating the impact of antioxidant addition in FLA APGD OES to reduce matrix effects originating from concomitant elements lead to enhancing analyte signals by up to 4.5-fold, improving efficiency in analyte transport. The proposed approach proved suitable for analyses of simulated manganese steel and mineral water samples, with detection limits for Ag, Pb, and Zn ranging from 0.006 to 0.4 μg L-1 and excellent measurement precision and analyte recoveries.
MICROCHEMICAL JOURNAL
(2021)
Article
Chemistry, Analytical
Krzysztof Greda, Maja Welna, Anna Szymczycha-Madeja, Pawel Pohl
Summary: By combining ICP OES with a novel FIGA mode, a more sensitive determination of Hg was achieved. The proposed method showed a much higher analytical signal for Hg compared to conventional PN-ICP OES, resulting in a significantly improved detection limit (0.035 μg/L) and measurement precision (2.5%). It also offered a 4 times lower detection limit compared to CVG-ICP OES (0.15 μg/L).
Article
Physics, Fluids & Plasmas
Yarong Zhang, Junlin Fang, Shaofeng Xu, Ying Guo, Jianjun Shi
Summary: A two-dimensional self-consistent fluid model was developed to investigate the ignition process of radio frequency (RF) discharge in an atmospheric helium cascade glow discharge. The model considered the case where a pulsed discharge was excited ahead of the RF discharge by applying pulsed DC voltage and RF voltage to two parallel plate electrodes separately. The spatio-temporal distribution of electron, ion, electric field, and mean electron energy showed that the electron and ion localized in the vicinity of the RF electrode with the extinguishment of the pulsed discharge, while a sheath region formed above the pulsed electrode due to the space charge. This explained the asymmetric ignition of RF discharge in the interelectrode gap observed in experiments. The migration of ions towards the pulsed electrode allowed for stable operation of the RF discharge. Furthermore, the migration time of ions from the RF electrode to the pulsed electrode was estimated to be 3.0 μs, which was consistent with the calculated migration time of ions across the discharge gap.
PLASMA SOURCES SCIENCE & TECHNOLOGY
(2023)
Article
Spectroscopy
Sunil P. Badal, Paul B. Farnsworth, George C-Y Chan, Brian T. Molnar, Jessica R. Hellinger, Jacob T. Shelley
Summary: Plasma-based ambient desorption/ionization sources often use helium as the primary discharge gas, but studies show advantages of mixed-gas plasmas. Adding H-2 to helium can decrease reagent-ion signals while preserving analyte-ion signals. Nitrogen addition increases negative reagent ions for enhanced ion signal of specific compounds. Various molecular gases impact emission characteristics and plasma parameters in mixed-gas systems.
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
(2021)
Article
Chemistry, Analytical
Shuang Liu, Xin-Xin Xue, Yong-Liang Yu, Jian-Hua Wang
Summary: The use of miniaturized optical emission spectrometry devices and activated carbon electrode tips allows for rapid preconcentration and quantitative analysis of heavy metals in water, significantly enhancing sensitivity and practicality.
ANALYTICAL CHEMISTRY
(2021)
Article
Biochemistry & Molecular Biology
Dongli Dai, Yueqin Zhu, Zhenli Zhu, Rong Qian, Shangjun Zhuo, Anqi Liu, Xian Li, Wei Li, Qiao Chen
Summary: An atmospheric pressure glow discharge ionisation source was constructed for the study of dopamine oxidation process. Six cationic intermediates were directly detected by atmospheric pressure glow discharge mass spectrometry (APGD-MS) during the dopamine oxidation process catalysed by polyphenol oxidase (PPO). The structures of the dopamine o-semiquinone radical (DASQ) and leukodopaminochrome radical (LDAC(?)) intermediates, as well as the isomers of dopaminochrome (DAC) and 5,6-dihydroxyindole (DHI), were further characterised using tandem mass spectrometry with the introduction of TEMPO and D2O to APGD-MS.
Article
Chemistry, Analytical
Marcos Bouza, Julio Garcia-Martinez, Bienvenida Gilbert-Lopez, Sebastian Brandt, Juan F. Garcia-Reyes, Antonio Molina-Diaz, Joachim Franzke
Summary: Dielectric barrier discharge ionization (DBDI) is a versatile tool for small-molecule mass spectrometry applications, covering a wide range of molecules from polar to low polar. However, the complex plasma gas-phase interactions in DBDI have not been well studied. In this study, the ionization mechanisms of a two-ring DBDI ion source were evaluated using different discharge gases for vaporized liquid samples. The results showed that APCI and DBDI exhibited different ionization trends during PAH analysis, with APCI mainly producing [M + H]+ ions and DBDI showing the prevalence of charge exchange reactions. The addition of dopants in the gas phase shifted the ionization mechanisms towards charge exchange reactions and facilitated the formation of [M]??+ ion species.
ANALYTICAL CHEMISTRY
(2023)
Article
Physics, Fluids & Plasmas
A. Walsten, K. Xu, C. Sanderson, C. Ballmann, D. Matyas
Summary: The study showed that adjusting the external electric field, frequency, and gas mixture ratio can control the timing and intensity of nanosecond pulsed atmospheric pressure dielectric barrier glow discharge in helium with 1% of argon.
PHYSICS OF PLASMAS
(2021)
Article
Physics, Fluids & Plasmas
Yuri Akishev, Anton Balakirev, Michail Grushin, Vladimir Karalnik, Igor Kochetov, Anatoly Napartovich, Alexander Petryakov, Nikolay Trushkin
IEEE TRANSACTIONS ON PLASMA SCIENCE
(2015)
Article
Physics, Fluids & Plasmas
Yu Akishev, F. Arefi-Khonsari, A. Demir, M. Grushin, V. Karalnik, A. Petryakov, N. Trushkin
PLASMA SOURCES SCIENCE & TECHNOLOGY
(2015)
Article
Engineering, Electrical & Electronic
V. N. Gorshkov, M. E. Grushin, E. G. Lariontsev, I. I. Saveliev, N. I. Khokhlov
QUANTUM ELECTRONICS
(2016)
Article
Engineering, Electrical & Electronic
Yu. Yu. Kolbas, M. E. Grushin, V. N. Gorshkov
QUANTUM ELECTRONICS
(2018)
Article
Biotechnology & Applied Microbiology
E. N. Kobzev, G. V. Kireev, Yu. A. Rakitskii, I. I. Martovetskaya, V. A. Chugunov, V. P. Kholodenko, M. V. Khramov, Yu. S. Akishev, N. I. Trushkin, M. E. Grushin
APPLIED BIOCHEMISTRY AND MICROBIOLOGY
(2013)
Article
Physics, Fluids & Plasmas
Yuri Akishev, Mikhail Grushin, Vladimir Karalnik, Alex Petryakov, Philippe Supiot, Nikolay Trushkin
IEEE TRANSACTIONS ON PLASMA SCIENCE
(2011)
Article
Physics, Fluids & Plasmas
Yuri Akishev, Nikolay Trushkin, Michail Grushin, Alexander Petryakov, Vladimir Karal'nik
IEEE TRANSACTIONS ON PLASMA SCIENCE
(2012)
Article
Physics, Applied
Yuri Akishev, Grigory Aponin, Anton Balakirev, Michail Grushin, Vladimir Karalnik, Alexander Petryakov, Nikolay Trushkin
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2013)
Article
Physics, Applied
Yu Akishev, G. Aponin, A. Balakirev, M. Grushin, A. Petryakov, V. Karal'nik, N. Trushkin
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2013)
Article
Physics, Applied
V. F. Kopiev, Y. S. Akishev, I. V. Belyaev, N. K. Berezhetskaya, V. A. Bityurin, G. A. Faranosov, M. E. Grushin, A. I. Klimov, V. A. Kopiev, I. A. Kossyi, I. A. Moralev, N. N. Ostrikov, M. I. Taktakishvili, N. I. Trushkin, M. Yu Zaytsev
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2014)
Article
Physics, Fluids & Plasmas
A. N. Trushkin, M. E. Grushin, I. V. Kochetov, N. I. Trushkin, Yu. S. Akishev
PLASMA PHYSICS REPORTS
(2013)
Article
Physics, Applied
Elena Sysolyatina, Andrey Mukhachev, Maria Yurova, Michael Grushin, Vladimir Karalnik, Alexander Petryakov, Nikolay Trushkin, Svetlana Ermolaeva, Yuri Akishev
PLASMA PROCESSES AND POLYMERS
(2014)
Article
Physics, Fluids & Plasmas
Yuri Akishev, Gregory Aponin, Anton Balakirev, Mikhail Grushin, Vladimir Karalnik, Alexander Petryakov, Nikolay Trushkin
PLASMA SOURCES SCIENCE & TECHNOLOGY
(2011)
Article
Physics, Fluids & Plasmas
Yu Akishev, G. Aponin, A. Balakirev, M. Grushin, V. Karalnik, A. Petryakov, N. Trushkin
PLASMA SOURCES SCIENCE & TECHNOLOGY
(2013)
Article
Physics, Fluids & Plasmas
Yu S. Akishev, A. A. Balakirev, M. E. Grushin, V. B. Karalnik, M. A. Medvedev, A. Petryakov, N. Trushkin
PLASMA SOURCES SCIENCE & TECHNOLOGY
(2020)