4.6 Article

Multiferroic properties of Bi0.8Dy0.2-xLaxFeO3 nanoparticles

Journal

JOURNAL OF PHYSICS D-APPLIED PHYSICS
Volume 43, Issue 2, Pages -

Publisher

IOP PUBLISHING LTD
DOI: 10.1088/0022-3727/43/2/025403

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Funding

  1. Shanghai Nanotechnology Promotion Center [0852nm03200]
  2. Programme Scholarship Fund of Ecnu [52YB2010]
  3. East China Normal University

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Bi(0.8)Dy(0.2-x)LaxFeO(3) (BDLFOx) (x = 0, 0.10 and 0.20 respectively) nanoparticles were prepared by the ethylene glycol based sol-gel method. The influence of the average radius and the effective magnetic moment of Bi-site ion on the structure, magnetic and dielectric properties, and the effective magnetic susceptibility of BDLFO x nanoparticles was investigated. All the samples were indexed to the orthorhombic structure based on the results of x-ray diffraction. The grain size of the samples increased with the increase in Bi-site ionic average radius. The magnetization of the samples was found to decrease with the effective magnetic moment of Bi-site ion decreasing. The dielectric constant and loss were improved when the Bi-site ionic average radius decreased and the effective magnetic moment of the Bi-site ions increased. The enhanced magnetization M and the polarization P in nanoparticles made the effective magnetic susceptibility of the samples greatly enhanced, in particular for the sample of x = 0. Therefore we concluded that the small amount of substitution of Bi3+ ions by trivalent rare-earth ions with a smaller ionic radius than Bi3+ ion and a high magnetic moment in the nano-system was a way to improve the multiferroic properties of BiFeO3.

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