Journal
JOURNAL OF PHYSICS D-APPLIED PHYSICS
Volume 41, Issue 23, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/0022-3727/41/23/235501
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Funding
- National Natural Science Foundation of the People's Republic of China [10672150]
- National Key Laboratory Fund for Shock Wave and Detonation Physics Research
- National Basic Research Program (973 program)
- Natural Science Research of ChaoHu College [XLY-200813]
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Based on spectral investigation, the role of nanoaluminium in the combustion phase of pseudo-nanoaluminized micro-cyclic-[CH2N(NO2)](3) (RDX) induced by shock wave is determined. Time-resolved monochromatic emission spectra of AlO (Delta nu = -1, 0, +1 of X-2 Sigma(+)-B-2 Sigma(+)) indicated bimodal combustion behaviour as nanoaluminium burns in post-detonation of a nanoaluminized RDX (cyclic-[CH2N(NO2)](3)) explosive under an Ar atmosphere, which is in accord with the theoretical reaction temperature. As oxygen replaces Ar, a single emission peak of AlO is observed. The morphology of the condensed products is evaluated by transmission electron microscopy and scanning electron microscopy. Analyses of x-ray diffraction and XPS are also performed, concluding that only nano-alpha-Al2O3 is present in the O-2 atmosphere experiments, whereas in the Ar atmosphere, metastable gamma-and theta-Al2O3 also exist. AlN is one of the condensed products in Ar atmosphere experiments, which should form at the end of combustion as gamma-and theta-Al2O3.
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