Journal
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS
Volume 42, Issue 14, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/0953-4075/42/14/145004
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Funding
- Russian Foundation for Basic Research (RFBR) [07-02-00279a]
- Basic Research and Higher Education (BRHE) of the USCivilian Research& Development Foundation (CRDF)
- Russian Ministry of Education Science [RUXO010-VZ-06, Annex BP2M10]
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The static hyperpolarizabilities, oscillator-strength-distribution moments S-3 and polarizabilities for S-, P-and D-series of helium and alkali atoms in Rydberg states with principal quantum numbers n between 30 and 70 were calculated in the single-electron Fues' model potential approach. On the basis of the numerical data, three-term polynomials in powers of the effective principal quantum number have been proposed for rapid and accurate evaluations of the indicated characteristics for atoms in arbitrary highly excited states. Numerical values of the fourth-order coefficients in the field-power-series expansions for energies of S1/2-, P-1/2,P-3/2- and D-3/2,D-5/2-states were determined in satisfactory agreement with available data of experiments and theory for rubidium atoms. The numerical data for sodium atoms were used for evaluating the second-order and fourth-order contributions to the electric field magnitude which can tune into double resonance the two-photon transitions between Stark sublevels of the nP(J)- and (n + 1)P-J'-states via the (n + 1)S-1/2-state.
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