Journal
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
Volume 23, Issue 11, Pages 1074-1079Publisher
WILEY
DOI: 10.1002/poc.1757
Keywords
co-crystals; organic solid state luminescence; supramolecular interactions; supramolecular luminescent systems
Categories
Ask authors/readers for more resources
Supramolecular chemistry provides a versatile approach to tune organic solid state luminescence by controlling the molecular organization through weak interactions. In this study, we have successfully tuned the solid state luminescence of 2-cyano-3(4-(diphenylamino) phenyl) acrylic acid (CDPA) by co-crystallizing with substituted pyridines. The position of methyl group on the pyridine (4-picoline, 3-picoline, and 2-picoline) has a dramatic effect on the supramolecular interactions formed, from usual carboxylic acid-pyridine interactions to deprotonation of CDPA in the crystal lattice and that allows to tune the CDPA solid state luminescence from 587 to 548nm gradually. Copyright (C) 2010 John Wiley & Sons, Ltd.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available