Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 3, Issue 6, Pages 751-754Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jz300158s
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Funding
- ACS PRE [51052-NDI6]
- Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory
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We report double sigma-aromaticity in a surface-deposited cluster, Pd-4, on the TiO2 (110) surface. In the gas phase, Pd-4 adopts a tetrahedral structure. However, surface binding promotes a flat, a-aromatic cluster. This is the first time aromaticity has been found in surface-deposited clusters. The concept of aromaticity is expected to become instrumental in predicting and interpreting properties of such systems, much like it is for isolated molecules and clusters.
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