Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 1, Issue 9, Pages 1459-1462Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jz100406w
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- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DESC0000989]
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Nanoparticles functionalized with ionizable ligands can exist in either dispersed or aggregated states at the same value of pH. This bistability and the related hystreresis accompanying pH changes derive from a subtle interplay between electrostatic and van der Waals forces. A theoretical model allows one to control the range of over, which bistability is observed.
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