Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 1, Issue 15, Pages 2233-2238Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jz100637m
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Funding
- NSF [CHE 809093]
- Korean Government (MEST) [2009-0074609]
- University of Georgia Research Foundation
- UGA Office of the Vice President for Research
- Korean Institute of Science and Technology Information (KISTI)
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [809093] Funding Source: National Science Foundation
- National Research Foundation of Korea [2009-0074609] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Small (HCl)(m)(H2O)(n) clusters have been assembled in He droplets, and their spectra in the HCl stretch range (2500-3000 cm(-1)) have been obtained. In a recent He droplet study, a band at 2670 cm(-1) was assigned to the dissociated H3O+(H2O)(3)Cl- ion pair. In this work, we have revised the assignment of this band to a cyclic hydrogen-bonded form of the (HCl)(2)(H2O)(2) cluster based on careful measurements of the pickup pressure dependence as well as the transition moment angles associated with the HCl stretch vibrations, A number of vibrational bands due to small mixed clusters have also been observed. As the number of the captured water molecules increases, a broad feature appears that spans the 2550-2800 cm(-1) range. The possible origin of this spectral broadening in large (HCl)(m)(H2O)(n) clusters is discussed.
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