Article
Metallurgy & Metallurgical Engineering
Shaoyang Shen, Liuzhang Ouyang, Jiangwen Liu, Hui Wang, Xu-Sheng Yang, Min Zhu
Summary: A one-step high-energy ball milling process is used to in situ form ultrafine Ni nanoparticles and combine them with expanded graphite to synthesize a MgH2Ni-EG nanocomposite. The nanocomposite exhibits excellent hydrogen storage performance at both high and room temperatures.
JOURNAL OF MAGNESIUM AND ALLOYS
(2023)
Article
Chemistry, Physical
Jingjing Wu, Bo Yuan, Yuyang Gu, Yifan Zhang, Zhongyuan Yan, Lida Zhang, Xusheng Yang, Haijiao Zhang, Ling Bai, Ziquan Li, Zhen-Dong Huang
Summary: A multifunctional BiOCl/amorphous antimony oxide (AAO) hetero-hybrid with the molar ratio of Bi3+/Sb3+ in 1/3 (1-BOC/3-AAO) is successfully developed by scalable ball-milling strategy. It exhibits exceptional visible light photocatalytic degradation performance of RhB and superior anodic potassium ion storage performance for potassium ion batteries. The hetero-hybrid possesses large specific surface area, narrow band gap, improved utilization of visible light, effectively suppressed recombination and highly enhanced transfer efficiency of the photogenerated charge carriers.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Materials Science, Multidisciplinary
Shaojie Lv, Hong-Hui Wu, Kaiyang Wang, Shuize Wang, Guilin Wu, Junheng Gao, Xu-Sheng Yang, Jiaming Zhu, Xinping Mao
Summary: The influences of cooling rates, prior austenite grain size, and impurity inclusion density on the microstructure evolution of austenite-acicular ferrite transformation in low alloy steels were quantitatively evaluated by multi-phase-field simulation. The numerical results demonstrate that reducing prior austenite grain size, increasing cooling rate, and increasing inclusion nucleation density can effectively refine acicular ferrite grain size. The findings contribute to better regulating and designing acicular ferrite in steels.
COMPUTATIONAL MATERIALS SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Wanting Sun, Jiasi Luo, Yim Ying Chan, J. H. Luan, Xu-Sheng Yang
Summary: In this study, a laser surface remelting technique was used to fabricate a heterogeneous gradient nanostructured layer on an austenitic Hadfield manganese steel. The layer exhibited a gradient refinement process and had a core-shell structure with ultra-strong mechanical properties due to the extra work hardening ability induced by the strength-ductility synergy in the gradient nanostructure.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Materials Science, Multidisciplinary
Jiasi Luo, Wanting Sun, Dingshan Liang, Wenqing Yang, K. C. Chan, Fuzeng Ren, Xu-Sheng Yang
Summary: Heterogeneous crystalline-amorphous nanostructures exhibit superior strength-ductility synergy through the cooperative effects of nanograins and amorphous grain boundaries in co-deformation. In this study, a facile laser surface remelting technique was successfully developed to fabricate a 100 μm-thick gradient nanostructured layer with phase decomposition on a TiZrHfTaNb0.2 high-entropy alloy. A 5 μm-thick crystalline-amorphous nanostructured surface layer with an average grain size of 7 nm was obtained. This nanostructured layer demonstrated an ultrahigh yield strength of 6.0 GPa and a compression strain of 25% during localized micro-pillar compression tests. Co-deformation cooperative mechanisms observed included well-retained dislocation activities in nanograins and crystallization in amorphous grain boundaries, resulting in grain coarsening through grain boundary-mediated plasticity. This study provides insights into the development of high-performance high-entropy alloys with novel crystalline-amorphous nanostructures and their plastic deformation mechanisms.
MATERIALS & DESIGN
(2023)
Article
Nanoscience & Nanotechnology
Rongjian Shi, Yanlin Wang, Supeng Lu, Saiyu Liu, Yanqi Tu, Shani Yang, Kewei Gao, Xu-Sheng Yang, Xiaolu Pang
Summary: The high-strength spring steel demonstrates superior hydrogen embrittlement resistance and satisfactory work hardening capacity after hydrogen pre-charging with dispersed multiple precipitates via multi-microalloying of 1.04 wt% Cr and 0.14 wt% V. The multiple precipitates include isolated (Mn, Cr, V)-enriched cementite, isolated V-enriched VC, and co-precipitation of cementite and VC, which act as effective hydrogen traps and reduce HE susceptibility by 23%, making this strategy beneficial for designing high-strength and HE-resistant automotive steels.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2023)
Article
Materials Science, Multidisciplinary
De-Xin Zhu, Kun-Ming Pan, Yuan Wu, Xiao-Ye Zhou, Xiang-Yue Li, Yong-Peng Ren, Sai-Ru Shi, Hua Yu, Shi-Zhong Wei, Hong-Hui Wu, Xu-Sheng Yang
Summary: In this study, the dominant factors influencing the bulk modulus of intermetallic compounds were identified as B-cal, dB(avg), and TIE. Surrogate machine learning models using these features achieved a 95% accuracy in predicting bulk modulus. Symbolic regression provided an expression for the relationship between bulk modulus and the screened features. These findings offer a new approach for optimizing and predicting the bulk moduli of intermetallic compounds.
Article
Metallurgy & Metallurgical Engineering
Rongjian Shi, Yanqi Tu, Liang Yang, Saiyu Liu, Shani Yang, Kewei Gao, Xu-Sheng Yang, Xiaolu Pang
Summary: This study explored the influence of pre-strain and microstructures on the hydrogen trapping behaviors in 1-GPa high-strength martensitic steel. The results showed that the trapped reversible and trapped irreversible hydrogen contents significantly increased after a pre-strain of 5%. The microstructural evolution revealed that the presence of concomitant dislocation cell-twin duplex microstructure and tangled dislocations contributed to the enhanced hydrogen trapping.
ACTA METALLURGICA SINICA-ENGLISH LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Yongyang Zhu, Shaoyang Shen, Xu-Sheng Yang, Liming Zeng, Gary Tsui, Zheng-Long Xu, Qing Zhou, Renheng Tang, K. C. Chan
Summary: This study proposes a cost-effective method to regenerate LiBH4 by ball milling hydrous lithium metaborate with low-cost Mg-based alloys. The introduction of light rare-earth metals into Mg improves the regeneration kinetics of LiBH4 by facilitating the breakage of B-O and conversion of H+ into H-. A yield of 40% can be achieved for LiBO2 center dot 2H(2)O-CeMg12 system with a relatively short ball milling duration of 10 hours. The optimized regeneration of LiBH4 is believed to be efficient and economical, utilizing an intrinsic hydrogen source in LiBO2 center dot 2H(2)O and cheap reducing agents. This finding is expected to promote the widespread use of LiBH4 for hydrogen storage.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Materials Science, Multidisciplinary
Shaojie Lv, Hong-Hui Wu, Kaiyang Wang, Jiaming Zhu, Shuize Wang, Guilin Wu, Junheng Gao, Xu-Sheng Yang, Xinping Mao
Summary: The austenite to ferrite phase transformation is a crucial structural change in steel production, with the ferrite morphology and grain size significantly impacting the mechanical properties of steel materials. This study investigates the effects of cooling rate, prior austenite grain size (PAGS), and Mn content on the microstructure evolution of the austenite-to-polygonal ferrite phase transformation using a multi-phase-field model. The findings reveal that higher cooling rates enhance the driving force for the phase transformation and delay the process. Decreasing PAGS increases the proportion of austenite grain boundaries, providing more nucleation sites for polygonal ferrite and resulting in refined grain size. Furthermore, increased Mn content leads to significant grain refinement by reducing the transformation temperature. This work provides valuable insights for adjusting and designing desired microstructures of polygonal ferrite to enhance the mechanical performance of steel.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Nanoscience & Nanotechnology
Yuqing Cai, Wenjing Liu, Fangfei Chang, Su Jin, Xusheng Yang, Chuanxiang Zhang, Ling Bai, Titus Masese, Ziquan Li, Zhen-Dong Huang
Summary: In this study, Ni, Fe, Mg, and Ti elements were introduced into Mn-based layered oxide to design a high-entropy compound HE-KMO, which demonstrated exceptional rate capability and cyclic stability.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Ling Wang, Dongxuan Li, Yawen Huang, Ruiqi Mao, Boqing Zhang, Fengxiong Luo, Peiyang Gu, Ping Song, Xiang Ge, Jian Lu, Xusheng Yang, Yujiang Fan, Xingdong Zhang, Kefeng Wang
Summary: In this study, enhanced in situ mineralization through the combination of enzymatic and anion-boosted mineralization is applied, resulting in improved mineralization efficiency, mineral content, and mechanical properties. The mechanism of mineralization enhancement is investigated through computational calculations and in vitro mineralization experiments. The strategy is shown to have potential applications in cranial bone repair.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Materials Science, Coatings & Films
Haoling Huo, Lin Cao, Jie Li, Huaijun Lin, Qiwei Wang, Xusheng Yang, Chuanjun Zang, Jingtao Zhang, Peng Zhang, Wei Li
Summary: In this study, modified coatings with PEEK and nanoparticles were utilized to enhance the strength and wear resistance. The addition of tantalum carbide nanoparticles showed the greatest improvement in mechanical behavior and wear resistance. The modified coatings have the potential to reduce stress on the titanium implant substrate and extend the lifespan of total knee replacement implants.
SURFACE & COATINGS TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Yanyu Chen, Jie Li, Yingfei Yang, Junjie Yang, Huaijun Lin, Qiwei Wang, Xusheng Yang, Yuying Meng, Wei Li, Zhidan Lin, Peng Zhang
Summary: A novel porous polymer was prepared using the Pickering high internal phase emulsion (HIPE) template method for efficient oil-water separation from sewage. The addition of OTS-modified carbon nanotubes and surfactants improved the stability, mechanical properties, and separation efficiency of the polyHIPE. The 1%OTS-CNT polyHIPE exhibited high oil absorption capacity and maintained absorption efficiency even after multiple reapplications. Furthermore, the polymer showed superior antibacterial properties against E. coli and S. aureus.
Article
Engineering, Environmental
Yongyang Zhu, Xubo Li, Xu-Sheng Yang, Pengyun Chen, Gary Chi-Pong Tsui, Zheng-Long Xu, Renheng Tang, Fangming Xiao, Kangcheung Chan
Summary: Researchers have developed a low-cost BCC solid solution alloy with excellent activation performance and high effective hydrogen desorption capacity by using a new compositionally complex doping strategy. The synergistic effect of Nb, Fe, Co, Ni, and Mn elements has been confirmed to improve hydrogen storage performance.
CHEMICAL ENGINEERING JOURNAL
(2023)