4.6 Article

In Situ Spectroelectrochemical Investigation of Ge, Si, and SixGe1-x Electrodeposition from an Ionic Liquid

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 117, Issue 4, Pages 1722-1727

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp309646r

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Funding

  1. BMBF project HELION
  2. Lower Saxony graduate school GEENI

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We report on in situ UV-vis spectroscopic measurement during the electrodeposition of silicon, germanium, and silicon-germanium alloys from an ionic liquid. From the spectroscopic analysis, the potential-dependent formation and growth of Ge, Si, and SixGe1-x nanoparticles were evaluated. The possible formation of adlayers and an underpotential deposition of Si also discussed.

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