Article
Chemistry, Multidisciplinary
Zhi-Bin Jian, Jie Bie, Shuang Chen
Summary: Confined ammonia molecules form a stable new rhomboidal phase in graphene oxide/graphene nanosheets, showing liquid-like behavior at room temperature and high stability requiring significant strain to destroy. These rhomboidal NH3 monolayers offer diverse hydrogen-bonded networks and potential piezoelectricity for future device applications.
Article
Chemistry, Multidisciplinary
Yiming Zhang, Yinghao Ding, Xinxin Li, Debin Zheng, Jie Gao, Zhimou Yang
Summary: Zwitterionic polymer materials have been extensively studied, but zwitterionic peptides supramolecular hydrogel materials are rarely studied. In this study, the preparation of two zwitterionic hydrogels using self-assembled peptides were reported. The differences in structure and function of the zwitterion peptide hydrogels caused by the two preparation methods were compared, with the enzyme induced self-assembly method showing better solubility and lower cytotoxicity.
CHINESE CHEMICAL LETTERS
(2021)
Article
Chemistry, Physical
Jian Zhou, Leyun Li, Xuejiao J. Gao, Haiqing Wang
Summary: The family of 2D materials includes graphene, TMDs, MXenes, Xenes, and organic materials, which possess unique sheet-like morphology and unconventional physicochemical properties. However, exploring and preparing two-dimensional materials with desired characteristics through highly controlled strategy remains a major challenge.
Article
Multidisciplinary Sciences
Samuel J. Lounder, Ayse Asatekin
Summary: Research shows that water filtration membranes with cross-linked zwitterionic copolymer membranes exhibit high ion selectivity, controlling salt partitioning and diffusivity for efficient salt separation. These membranes also achieve high fluoride retention and high chloride passage in saline mixtures.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2021)
Article
Engineering, Chemical
Zheng Chen, Mingrui Liao, Lizhi Zhang, Jian Zhou
Summary: Zwitterionic materials show strong hydration and underwater oleophobicity, with optimal performance when the carbon spacer length is 3. The addition of NaCl can enhance the properties by weakening self-association of molecules.
Article
Chemistry, Physical
Tianqi Wu, Zedong Zhao, Jiajia Zhang, Chang Zhang, Yixuan Guo, Yongjie Cao, Shaoxue Pan, Yicheng Liu, Peiying Liu, Yuanhang Ge, Wei Liu, Lei Dong, Hongbin Lu
Summary: A high-performance thick electrode was fabricated through layer-by-layer assembly of two-dimensional nanosheets, allowing for abundant ion-transport channels. The new electrode exhibits excellent capacity and areal capacity, marking a significant stride towards higher energy density.
ENERGY STORAGE MATERIALS
(2021)
Article
Chemistry, Physical
Jianfeng Li, Wei Cao, Jinjin Li, Ming Ma
Summary: The study revealed that fluorination of perfluorocarbon SAM enhances superlubricity performance, achieving significantly lower friction coefficient and greater load-bearing capacity between graphite in water.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Nanoscience & Nanotechnology
Jihyuk Yang, Mojun Chen, Heekwon Lee, Zhaoyi Xu, Zhiwen Zhou, Shien-Ping Feng, Ji Tae Kim
Summary: Peptide-based materials are being used as smart building blocks for nanobiodevices due to their programmable properties, with recent advancements allowing for the fabrication of freeform, crystalline peptide structures using a combination of meniscus-guided 3D printing and molecular self-assembly. This approach enables layer-by-layer, crystalline 3D printing with high spatial resolution and the potential for piezoelectric behavior, suggesting promising applications in bioelectronic devices.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Guy Wiernik, Narendra Kumar Mishra, Sudipta Mondal, Rafat Ali, Ehud Gazit, Sandeep Verma
Summary: Structural colors in nature have advantages over pigment-based colors, including higher durability, brilliance, and hydrophobicity, making them ideal for technological applications. Researchers have successfully created artificial topologies combining structural coloration and hydrophobicity through biomimetics, demonstrating simple techniques for controlled surface coloration.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Ty Christoff-Tempesta, Elad Deiss-Yehiely, Pierre C. Dromel, Linnaea D. Uliassi, Cecile A. C. Chazot, Eveline Postelnicu, A. John Hart, Myron Spector, Paula T. Hammond, Julia H. Ortony
Summary: This study reports the self-assembly of strongly interacting small molecule amphiphiles into nanoribbons for antifouling coatings. The coated surfaces show significant reduction in protein adsorption, bacterial biofilm formation, and cell adhesion.
ADVANCED MATERIALS INTERFACES
(2022)
Article
Materials Science, Multidisciplinary
Hui Wang, Shuwei Sun, Lingyao Kong, Wei Zhang, Ying Bai, Min Feng
Summary: Recent research on carbon materials has revealed that they can form various structures, including three-dimensional carbon allotropes. While the piezoelectric properties of these allotropes have not been extensively studied, calculations show promising results, indicating potential applications in active sensors and actuators.
JOURNAL OF MATERIALS SCIENCE
(2021)
Article
Engineering, Chemical
Xin Qian, Tulasi Ravindran, Samuel J. Lounder, Ayse Asatekin, Jeffrey R. McCutcheon
Summary: The study evaluates the use of electrospray to print thin layers of amphiphilic zwitterionic selective layers onto UF membrane substrates, resulting in increased water permeance while maintaining dye rejection as thickness is reduced. Thickness of polymer films affects rejection and permeability, with annealing found to increase permeance without significant loss of rejection.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Ji Hoon Kim, Ji Min Kim, Gil Won Lee, Gyu Hyeon Shim, Sun Taek Lim, Koung Moon Kim, Thi To Nguyen Vo, Boyeon Kweon, Somchai Wongwises, Dong Wook Jerng, Moo Hwan Kim, Ho Seon Ahn
Summary: Researchers have developed a simple method for the formation of large-scale 3D graphene networks, with the structural morphology of the network being modifiable by controlling vaporization rate, surface temperature of the target substrate, and amount of discharged colloids. The self-assembled graphene possesses excellent electrical and mechanical properties, making it suitable for mass production of graphene-based materials.
Article
Chemistry, Physical
Weiqi Kong, Jiayu Li, Jiaxu Gong, Qinlin Yu, Guohui Chen, Junshu Chen, Yatang Dai, Linyu Pu, Huan Zhang, Wei Wang
Summary: Recently, the construction of morphology and structure has been recognized as a key factor in enhancing the cycle stability and rate performance of nanomaterials. In this study, three-dimensional network structured MnCo2S4/NiCo2S4 (MCS/NCS) composites were synthesized by simple electrodeposition of NiCo2S4 nanosheets onto the framework of MnCo2S4 nanosheets. The MCS/NCS composites exhibited better capacitive and conductive properties compared to the two-dimensional nanosheet structures. Furthermore, the effects of electrodeposition time on the morphology and electrochemical properties of the composites were investigated. Among them, MCS/NCS-6 showed a unique structure and excellent electrochemical properties, demonstrating remarkable specific capacity (920 C g-1 at a current density of 1 A g-1) and good cycling stability. Additionally, the fabricated asymmetric supercapacitor MCS/NCS//AC assembly displayed a high energy density of 45.6 Wh kg-1 (800 W kg-1 power density) and good cycle life (75.6%, 10,000 cycles), indicating the potential application of this uniquely structured electrode material in alkaline aqueous energy storage devices such as asymmetric supercapacitors.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Review
Chemistry, Physical
Jiaojiao Ma, Kaiwen Guan, Yu Jiang, Yang Cao, Sheng Hu
Summary: Research on two-dimensional materials has provided insights into the low-dimensional science and the investigation of physical and chemical processes under two-dimensional confinement. The discoveries in this field have expanded our understanding of nano-science and stimulated the development of potential applications.