Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 113, Issue 32, Pages 14067-14070Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp904937c
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We investigate nonradiative decay ill the (16,16) armchair graphene nanoribbon (GNR) using surface-hopping with decoherence in a time-dependent Kohn-Sham scheme, The lowest singlet excitation decays within 300 ps in the ideal GNR by coupling to the 1450 cm(-1) disorder mode associated with edges. The C-2-insertion defect doubles the decay rate. Compared to carbon nanotubes (CNTs), GNRs are more anharmonic and show faster phonon-induced pure dephasing of electronic transitions. Defects relieve strain better and, therefore, exhibit weaker electron-phonon coupling in GNRs than CNTs. The slower nonradiative decay of GNRs compared to similar size CNTs makes GNRs better candidates for the semiconductor applications.
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