4.6 Article

Nanocomposites of Iron-Cobalt Alloy and Magnetite: Controllable Solvothermal Synthesis and Their Magnetic Properties

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 113, Issue 46, Pages 19875-19882

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp909049b

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Funding

  1. National Natural Science Foundation of China [50872040]

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Nanocomposites of Fe-Co alloy and cobalt-substituted magnetite magnetic materials FexCo1-x/CoyRezFe3-y-zO4 (Re = none, La, Nd, and Gd) have been obtained successfully employing a surfactant-assisted solvothermal method. The nanocomposite features hard and soft magnetic phases juxtaposed within one discrete, anisotropic structure. Sodium oleate molecules were found effective in preventing the oxidation of the Fe-Co alloy and aggregation of the magnetic microspheres. X-ray diffraction, X-ray photoelectron spectroscopy, field emission scanning electron microscopy, and transmission electron microscopy were used to characterize the structure and the morphology of the products. The result of magnetic characterization reveals that the magnetic microspheres exhibit a ferromagnetic behavior and possess high saturation magnetization and low coercivity. It is expected that these magnetic microspheres with uniform size would have potential applications Such as magnetic carriers for drug targeting because of their excellent soft-magnetic properties.

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