Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 112, Issue 14, Pages 5241-5244Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp7114548
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Voltage-controlled conductance hysteresis and stepwise switching in a reversible manner were observed in a single-molecule double-barrier junction defined by a scanning tunneling microscope (STM) at similar to 10 K. In situ visualization and characterization of the junction using the STM revealed that the charge bistability of a single molecule on a polar alumina film is responsible for the conductance hysteresis and switching. It was also found that the relative stability between different charge states depends on the multiple adsorption configurations of molecules on the surface.
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