Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 117, Issue 49, Pages 15369-15385Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp4046403
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Funding
- Singapore National Research Foundation [NRF-CRP5-2009-04]
- Singapore Agency for Science, Technology and Research Science and Engineering, (A*STAR SERC) [102-149-0153]
- Nanyang President's Graduate Scholarship
- Lee Kuan Yew Postdoctoral Fellowship
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We present the theoretical details and experimental demonstration of fifth-order three-dimensional (3D) electronic spectroscopy using a pump probe beam geometry. This is achieved using a pulse shaper and appropriate phase cycling schemes. We show how 8-step and 27-step phase cycling schemes can measure purely absorptive 3D spectra as well as 3D spectra for the individual fifth-order processes that contribute to the purely absorptive spectrum. 3D spectra as a function of two separate controllable waiting time periods can be obtained. The peak shapes and positions of the peaks in the experimental measurement correspond well to theory.
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