4.5 Article

The liquid-glass and liquid-liquid transitions of TPP at elevated pressure

Journal

JOURNAL OF PHYSICAL CHEMISTRY B
Volume 112, Issue 34, Pages 10383-10385

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp8042158

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Funding

  1. Polish Ministry of Sciences and Information Technology [N202 14732/4240]

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We studied the polyamorphism of the liquid triphenyl phosphite by means of broadband dielectric spectroscopy at ambient and elevated(p = 500 MPa) pressures. The effect of pressure oil fragility, liquid-liquid phase transition, and its kinetics is discussed in relation to the two-order-parameter model proposed by Tanaka. The experimental evidence in support of this model is presented.

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