Journal
JOURNAL OF PHYSICAL CHEMISTRY A
Volume 114, Issue 34, Pages 9022-9027Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp908450c
Keywords
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Funding
- National Science Foundation, U.S. Japan cooperative science [CHE 0809093, INT 0233203]
- JSPS (Japan Society for the Promotion of Science)
- Natural Sciences and Engineering Research Council of Canada
- NSF
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Infrared spectra and intensities of the nu(3) band of H2O in Ar-H2O and O-2-H2O complexes have been studied by helium nanodroplet spectroscopy. It was found that the H2O molecule rotates almost freely in both the Ar-H2O and O-2-H2O complexes. Infrared intensities of the nu(3) band of H2O in these complexes were equal to that of an isolated H2O molecule within experimental errors. The obtained infrared spectra and infrared intensities were compared with those of the N-2-H2O complex in helium droplets, which we recently reported.
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