Journal
JOURNAL OF PETROLOGY
Volume 50, Issue 10, Pages 1955-1971Publisher
OXFORD UNIV PRESS
DOI: 10.1093/petrology/egp063
Keywords
carbonatites; alkaline silicate rocks; liquid immiscibility; assimilation; radiogenic isotopes
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Carbonatites commonly occur together with alkaline silicate rocks. It is frequently argued in the literature that the varied Sr-87/Sr-86, Nd-143/Nd-144 and Pb isotopic ratios in the alkaline silicate rocks reflect source heterogeneity, and that in many cases bear no genetic significance to the coexistence of silicates and carbonatites. Such a hypothesis may not be universal as it fails to explain the observations that in numerous carbonatite-alkaline complexes both rock types are contemporaneous. they exhibit complementary trace element patterns'. and most importantly their initial radiogenic isotopic ratios overlap, all of which when considered together suggest a common parentage. In addition, the alkaline silicate rocks have more variable and higher Sr-87/Sr-86, and lower Nd-143/Nd-144 and Pb isotopic ratios compared with those of the carbonatites and show lyperbolic trends in isotopic ratio vs concentration plots, hinting at a possible contamination of their parental magma by crustal or lithospheric material. Using a mathematical model that quantifies the isotopic ratios and concentrations of an element during concurrent assimilation and fractional crystallization of silicate rocks combined with immiscible separation of carbonate melt (AFCLI), I propose that the isotopic ratio variations in most carbonatite-alkaline silicate complexes can be explained by assimilation of crustal material by parental carbonated silicate parental magmas. A highly plausible scenario that emerges from this exercise is that not ono are the carbonate and associated silicate magmas derived from a single parental magma, but also that the lower crust plays an important role in their diversification.
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