4.6 Article

Unconventional superconductivity in quasi-one-dimensional Rb2Cr3As3

Journal

PHYSICAL REVIEW B
Volume 91, Issue 2, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.91.020506

Keywords

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Funding

  1. National Basic Research Program of China [2011CBA00103]
  2. NSFC [11190023]
  3. Fundamental Research Funds for the Central Universities of China

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Following the discovery of superconductivity in quasi-one-dimensional K2Cr3As3 containing [(Cr3As3)(2-)](infinity) chains (J. K. Bao et al., arXiv: 1412.0067), we succeeded in synthesizing an analogous compound, Rb2Cr3As3, which also crystallizes in a hexagonal lattice. The replacement of K by Rb results in an expansion of the a axis by 3%, indicating a weaker interchain coupling in Rb2Cr3As3. Bulk superconductivity emerges at 4.8 K, above which the normal-state resistivity shows a linear temperature dependence up to 35 K. The estimated upper critical field at zero temperature exceeds the Pauli paramagnetic limit by a factor of 2. Furthermore, the electronic specific-heat coefficient extrapolated to zero temperature in the mixed state increases with root H, suggesting the existence of nodes in the superconducting energy gap. Hence Rb2Cr3As3 manifests itself as another example of an unconventional superconductor in the Cr3As3-chain based system.

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