Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 766, Issue -, Pages 40-48Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2014.04.035
Keywords
Ferrocene; Phosphinic acid; Structure; Hydrogen bond
Categories
Funding
- Russian Foundation for Basic Research [12-03-00483]
- Ministerium of Science And Education of Russian Federation [8446]
- DAAD
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The series of ferrocenylphosphinic acids Fc(P(R)(O)(OH)) (1a-d) and ferrocene-1,1'-diyl-phosphinic acids Fc(P(R)(O)(OH))(2)(2a-d) (R H (a), Me (b), Et (c), Ph (d)) have been obtained and studied using X-ray single crystal diffraction, IR-spectroscopy and quantum chemistry. The intermolecular hydrogen bonding in 1a-d proceeds highly stereoselectively and results in formation of racemic conglomerate of 1d. The formation of inter-and intra-molecular hydrogen bonds for disubstituted acids 2c-d depends on substituent at phosphorus atoms. (C) 2014 Elsevier B. V. All rights reserved.
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