4.5 Article

New nitrochromenylmethylidene-containing ruthenium metathesis catalyst

Journal

JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 701, Issue -, Pages 87-92

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2011.12.024

Keywords

Olefin metathesis; Ruthenium catalyst; Chromene; Methylidene complex

Funding

  1. Ministry of Science and Higher Education [N N204 154936]

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New Hoveyda-Grubbs type catalyst containing nitrochromenyl ligand is reported herein. The catalyst was tested in model RCM, CM and enyne reactions. Its activity was compared with that of commercially available complexes and with literature data for Grela catalyst. New catalyst appeared to be fast initiating, but less stable than other catalysts. (C) 2012 Elsevier B.V. All rights reserved.

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