Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 700, Issue -, Pages 132-134Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2011.11.030
Keywords
N-Heterocyclic carbene; Palladium complex; Hiyama reaction; Aryl chloride; Synthetic method
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Funding
- National Natural Science Foundation of China [21002072]
- Opening Foundation of Zhejiang Provincial Top Key Discipline [100061200123]
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A well-defined NHC-Pd(II)-Im complex was proved to be an efficient catalyst for the Hiyama reaction of a variety of aryl chlorides with aryltrimethoxysilanes. Under the optimal conditions, all reactions took place smoothly to give the corresponding coupling products in moderate to high yields. (C) 2011 Elsevier B. V. All rights reserved.
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