Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 694, Issue 15, Pages 2336-2342Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2009.03.035
Keywords
Molecular conductors; 8,8 '-Diiodo-3,3 '-cobalt bis(1,2-dicarbollide); Tetrathiafulvalenium; Bis( methylenedithio)-tetrathiafulvalenium; Bis(ethylenedithio)-tetrathiafulvalenium; Crystal structure
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Funding
- Russian Foundation for Basic Research [07-03-00712, 08-03-12043]
- Russian President Grant [MR-190.2007.3]
- Program of the Presidium of Russian Academy of Sciences
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New molecular conductors on the base of 8,8'-diiodo cobalt bis(dicarbollide) anion (TTF)[8,8'-I-2-3,3'-Co(1,2-C2B9H10)(2)] (1), (BMDT-TTF)(4)[8,8'-I-2-3,3'-Co(1,2-C2B9H10)(2)] (2) and (BEDT-TTF)(2)[8,8'-I-2-3,3'-Co(1,2-C2B9H10)(2)] (3) were synthesized and their crystal structures and electrical conductivities were determined. All the radical cation salts prepared were found to be semiconductors. Some regularities in the crystal structures of the TTF-based radical cation salts with bis(dicarbollide) complexes of transition metals are discussed. (C) 2009 Elsevier B.V. All rights reserved.
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